INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES

The infuence of some arylazo indole derivatives on the corrosion rate of 70/30 a-brass in 2 mol 1-1 HNO3 was investigated using weight loss and galvanostatic polarization techniques. It was found that the investigated compounds behave as inhibitors. The inhibition effciency increases with increasing...

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Autores principales: FOUDA,A. S, MAHFOUZ,H
Lenguaje:English
Publicado: Sociedad Chilena de Química 2009
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400019
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spelling oai:scielo:S0717-970720090004000192010-04-15INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVESFOUDA,A. SMAHFOUZ,H corrosion inhibition a-brass synergistic effect HNO3 arylazo indole derivatives The infuence of some arylazo indole derivatives on the corrosion rate of 70/30 a-brass in 2 mol 1-1 HNO3 was investigated using weight loss and galvanostatic polarization techniques. It was found that the investigated compounds behave as inhibitors. The inhibition effciency increases with increasing the inhibitor concentration, but decreases with increasing the temperature. The adsorption of these compounds on the a-brass surface follows a Frumkin’s adsorption isotherm. The electrochemical results indicated that all the investigated compounds act as mixed-type inhibitors. The infuence of the substituent group on the inhibition effciency of the inhibitor was explained in terms of the density of the electron cloud on arylazo indole moiety. Some thermodynamic parameters for corrosion and adsorption processes were determined and discussed.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.4 20092009-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400019en10.4067/S0717-97072009000400019
institution Scielo Chile
collection Scielo Chile
language English
topic corrosion inhibition
a-brass
synergistic effect
HNO3
arylazo indole derivatives
spellingShingle corrosion inhibition
a-brass
synergistic effect
HNO3
arylazo indole derivatives
FOUDA,A. S
MAHFOUZ,H
INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES
description The infuence of some arylazo indole derivatives on the corrosion rate of 70/30 a-brass in 2 mol 1-1 HNO3 was investigated using weight loss and galvanostatic polarization techniques. It was found that the investigated compounds behave as inhibitors. The inhibition effciency increases with increasing the inhibitor concentration, but decreases with increasing the temperature. The adsorption of these compounds on the a-brass surface follows a Frumkin’s adsorption isotherm. The electrochemical results indicated that all the investigated compounds act as mixed-type inhibitors. The infuence of the substituent group on the inhibition effciency of the inhibitor was explained in terms of the density of the electron cloud on arylazo indole moiety. Some thermodynamic parameters for corrosion and adsorption processes were determined and discussed.
author FOUDA,A. S
MAHFOUZ,H
author_facet FOUDA,A. S
MAHFOUZ,H
author_sort FOUDA,A. S
title INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES
title_short INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES
title_full INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES
title_fullStr INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES
title_full_unstemmed INHIBITION OF CORROSION OF Α-BRASS (Cu-Zn, 67/33) IN HNO3 SOLUTIONS BY SOME ARYLAZO INDOLE DERIVATIVES
title_sort inhibition of corrosion of Α-brass (cu-zn, 67/33) in hno3 solutions by some arylazo indole derivatives
publisher Sociedad Chilena de Química
publishDate 2009
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400019
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AT mahfouzh inhibitionofcorrosionof913brasscuzn6733inhno3solutionsbysomearylazoindolederivatives
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