STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY
After cellulose, lignin is, the second most abundant component in wood. In the pulping industry, the introduction of modern Kraft pulping technologies could produce chemical modifcation in lignins functional groups. Kraft lignins from Eucaliptus nitens and Pinus radiata industrial black liquors wer...
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Sociedad Chilena de Química
2009
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oai:scielo:S0717-970720090004000302010-04-15STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRYLISPERGUER,JUSTOPEREZ,PATRICIOURIZAR,SILVIO lignins infrared spectroscopy glass transition temperatures After cellulose, lignin is, the second most abundant component in wood. In the pulping industry, the introduction of modern Kraft pulping technologies could produce chemical modifcation in lignins functional groups. Kraft lignins from Eucaliptus nitens and Pinus radiata industrial black liquors were isolated by acid precipitation. An organosolv lignin was obtained from spent liquor from the P.radiata wood pulping process. All lignins were acetylated with acetic anhydride and characterized by Fourier-transformed infrared spectroscopy (FT-IR) . Analysis based on the IR-fngerprint spectral region indicates several differences in the functional groups of the different types of lignins. The thermal behaviour of unmodifed and acetylated lignins were studied by differential scanning calorimetry (DSC) and the glass transition temperatures (Tg) were determined and compared with values reported in the literature. The acetylated lignins show a decrease in the Tg values which is probably due, to the at plasticization effect of the acetylation reaction.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.4 20092009-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400030en10.4067/S0717-97072009000400030 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
lignins infrared spectroscopy glass transition temperatures |
| spellingShingle |
lignins infrared spectroscopy glass transition temperatures LISPERGUER,JUSTO PEREZ,PATRICIO URIZAR,SILVIO STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY |
| description |
After cellulose, lignin is, the second most abundant component in wood. In the pulping industry, the introduction of modern Kraft pulping technologies could produce chemical modifcation in lignins functional groups. Kraft lignins from Eucaliptus nitens and Pinus radiata industrial black liquors were isolated by acid precipitation. An organosolv lignin was obtained from spent liquor from the P.radiata wood pulping process. All lignins were acetylated with acetic anhydride and characterized by Fourier-transformed infrared spectroscopy (FT-IR) . Analysis based on the IR-fngerprint spectral region indicates several differences in the functional groups of the different types of lignins. The thermal behaviour of unmodifed and acetylated lignins were studied by differential scanning calorimetry (DSC) and the glass transition temperatures (Tg) were determined and compared with values reported in the literature. The acetylated lignins show a decrease in the Tg values which is probably due, to the at plasticization effect of the acetylation reaction. |
| author |
LISPERGUER,JUSTO PEREZ,PATRICIO URIZAR,SILVIO |
| author_facet |
LISPERGUER,JUSTO PEREZ,PATRICIO URIZAR,SILVIO |
| author_sort |
LISPERGUER,JUSTO |
| title |
STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY |
| title_short |
STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY |
| title_full |
STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY |
| title_fullStr |
STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY |
| title_full_unstemmed |
STRUCTURE AND THERMAL PROPERTIES OF LIGNINS: CHARACTERIZATION BY INFRARED SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMETRY |
| title_sort |
structure and thermal properties of lignins: characterization by infrared spectroscopy and differential scanning calorimetry |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2009 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400030 |
| work_keys_str_mv |
AT lisperguerjusto structureandthermalpropertiesofligninscharacterizationbyinfraredspectroscopyanddifferentialscanningcalorimetry AT perezpatricio structureandthermalpropertiesofligninscharacterizationbyinfraredspectroscopyanddifferentialscanningcalorimetry AT urizarsilvio structureandthermalpropertiesofligninscharacterizationbyinfraredspectroscopyanddifferentialscanningcalorimetry |
| _version_ |
1718445416026996736 |