THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
Tetraethylammonium Bromochromate, TEABC, Tetrahexylammonium Bromochromate, THexABC and Tetraheptylammonium Bromochromate, THepABC are new reagents used for almost quantitative conversion of alcohols into the corresponding aldehydes and ketones. These tetraalkylammonium bromochromate reagents are eas...
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Sociedad Chilena de Química
2009
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oai:scielo:S0717-970720090004000382010-04-15THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLSGHAMMAMY,SHAHRIAREMEHRANI,KHEYROLLAHAFRAND,HAMIDJAVANSHIR,ZAHRA REZAEIBÉHBAHANI,GHOLAMREZA MOGHIMI,ALI AGHBOLAGH,ZAHRA SHOKRI Chromium(VI) Tetraethylammonium Bromotrioxochromate Tetrahexylammonium Bromotrioxochromate Tetrahepthylammonium Bromotrioxochromate Oxidation Organic substrates Alcohols Tetraethylammonium Bromochromate, TEABC, Tetrahexylammonium Bromochromate, THexABC and Tetraheptylammonium Bromochromate, THepABC are new reagents used for almost quantitative conversion of alcohols into the corresponding aldehydes and ketones. These tetraalkylammonium bromochromate reagents are easily synthesized by the reaction of relative tetraalkylammonium bromide with a solution of CrO3 in a 1:1 mole ratio. These reagents are versatile agents for the effective and nearly quantitative oxidation of organic substrates, in particular for alcohols, under mild and acid-free conditions.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.4 20092009-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400038en10.4067/S0717-97072009000400038 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Chromium(VI) Tetraethylammonium Bromotrioxochromate Tetrahexylammonium Bromotrioxochromate Tetrahepthylammonium Bromotrioxochromate Oxidation Organic substrates Alcohols |
spellingShingle |
Chromium(VI) Tetraethylammonium Bromotrioxochromate Tetrahexylammonium Bromotrioxochromate Tetrahepthylammonium Bromotrioxochromate Oxidation Organic substrates Alcohols GHAMMAMY,SHAHRIARE MEHRANI,KHEYROLLAH AFRAND,HAMID JAVANSHIR,ZAHRA REZAEIBÉHBAHANI,GHOLAMREZA MOGHIMI,ALI AGHBOLAGH,ZAHRA SHOKRI THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS |
description |
Tetraethylammonium Bromochromate, TEABC, Tetrahexylammonium Bromochromate, THexABC and Tetraheptylammonium Bromochromate, THepABC are new reagents used for almost quantitative conversion of alcohols into the corresponding aldehydes and ketones. These tetraalkylammonium bromochromate reagents are easily synthesized by the reaction of relative tetraalkylammonium bromide with a solution of CrO3 in a 1:1 mole ratio. These reagents are versatile agents for the effective and nearly quantitative oxidation of organic substrates, in particular for alcohols, under mild and acid-free conditions. |
author |
GHAMMAMY,SHAHRIARE MEHRANI,KHEYROLLAH AFRAND,HAMID JAVANSHIR,ZAHRA REZAEIBÉHBAHANI,GHOLAMREZA MOGHIMI,ALI AGHBOLAGH,ZAHRA SHOKRI |
author_facet |
GHAMMAMY,SHAHRIARE MEHRANI,KHEYROLLAH AFRAND,HAMID JAVANSHIR,ZAHRA REZAEIBÉHBAHANI,GHOLAMREZA MOGHIMI,ALI AGHBOLAGH,ZAHRA SHOKRI |
author_sort |
GHAMMAMY,SHAHRIARE |
title |
THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS |
title_short |
THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS |
title_full |
THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS |
title_fullStr |
THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS |
title_full_unstemmed |
THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS |
title_sort |
three new tetraalkylammonium bromochromates, nr4 [cro3br], (r= et, hex, hep): mild and efficient reagents for oxidation of primary and secondary alcohols |
publisher |
Sociedad Chilena de Química |
publishDate |
2009 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400038 |
work_keys_str_mv |
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