THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS

Tetraethylammonium Bromochromate, TEABC, Tetrahexylammonium Bromochromate, THexABC and Tetraheptylammonium Bromochromate, THepABC are new reagents used for almost quantitative conversion of alcohols into the corresponding aldehydes and ketones. These tetraalkylammonium bromochromate reagents are eas...

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Autores principales: GHAMMAMY,SHAHRIARE, MEHRANI,KHEYROLLAH, AFRAND,HAMID, JAVANSHIR,ZAHRA  , REZAEIBÉHBAHANI,GHOLAMREZA  , MOGHIMI,ALI  , AGHBOLAGH,ZAHRA SHOKRI  
Lenguaje:English
Publicado: Sociedad Chilena de Química 2009
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400038
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spelling oai:scielo:S0717-970720090004000382010-04-15THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLSGHAMMAMY,SHAHRIAREMEHRANI,KHEYROLLAHAFRAND,HAMIDJAVANSHIR,ZAHRA  REZAEIBÉHBAHANI,GHOLAMREZA  MOGHIMI,ALI  AGHBOLAGH,ZAHRA SHOKRI   Chromium(VI) Tetraethylammonium Bromotrioxochromate Tetrahexylammonium Bromotrioxochromate Tetrahepthylammonium Bromotrioxochromate Oxidation Organic substrates Alcohols Tetraethylammonium Bromochromate, TEABC, Tetrahexylammonium Bromochromate, THexABC and Tetraheptylammonium Bromochromate, THepABC are new reagents used for almost quantitative conversion of alcohols into the corresponding aldehydes and ketones. These tetraalkylammonium bromochromate reagents are easily synthesized by the reaction of relative tetraalkylammonium bromide with a solution of CrO3 in a 1:1 mole ratio. These reagents are versatile agents for the effective and nearly quantitative oxidation of organic substrates, in particular for alcohols, under mild and acid-free conditions.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.54 n.4 20092009-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400038en10.4067/S0717-97072009000400038
institution Scielo Chile
collection Scielo Chile
language English
topic Chromium(VI)
Tetraethylammonium Bromotrioxochromate
Tetrahexylammonium Bromotrioxochromate
Tetrahepthylammonium Bromotrioxochromate
Oxidation
Organic substrates
Alcohols
spellingShingle Chromium(VI)
Tetraethylammonium Bromotrioxochromate
Tetrahexylammonium Bromotrioxochromate
Tetrahepthylammonium Bromotrioxochromate
Oxidation
Organic substrates
Alcohols
GHAMMAMY,SHAHRIARE
MEHRANI,KHEYROLLAH
AFRAND,HAMID
JAVANSHIR,ZAHRA  
REZAEIBÉHBAHANI,GHOLAMREZA  
MOGHIMI,ALI  
AGHBOLAGH,ZAHRA SHOKRI  
THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
description Tetraethylammonium Bromochromate, TEABC, Tetrahexylammonium Bromochromate, THexABC and Tetraheptylammonium Bromochromate, THepABC are new reagents used for almost quantitative conversion of alcohols into the corresponding aldehydes and ketones. These tetraalkylammonium bromochromate reagents are easily synthesized by the reaction of relative tetraalkylammonium bromide with a solution of CrO3 in a 1:1 mole ratio. These reagents are versatile agents for the effective and nearly quantitative oxidation of organic substrates, in particular for alcohols, under mild and acid-free conditions.
author GHAMMAMY,SHAHRIARE
MEHRANI,KHEYROLLAH
AFRAND,HAMID
JAVANSHIR,ZAHRA  
REZAEIBÉHBAHANI,GHOLAMREZA  
MOGHIMI,ALI  
AGHBOLAGH,ZAHRA SHOKRI  
author_facet GHAMMAMY,SHAHRIARE
MEHRANI,KHEYROLLAH
AFRAND,HAMID
JAVANSHIR,ZAHRA  
REZAEIBÉHBAHANI,GHOLAMREZA  
MOGHIMI,ALI  
AGHBOLAGH,ZAHRA SHOKRI  
author_sort GHAMMAMY,SHAHRIARE
title THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
title_short THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
title_full THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
title_fullStr THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
title_full_unstemmed THREE NEW TETRAALKYLAMMONIUM BROMOCHROMATES, NR4 [CRO3BR], (R= ET, HEX, HEP): MILD AND EFFICIENT REAGENTS FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS
title_sort three new tetraalkylammonium bromochromates, nr4 [cro3br], (r= et, hex, hep): mild and efficient reagents for oxidation of primary and secondary alcohols
publisher Sociedad Chilena de Química
publishDate 2009
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000400038
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