HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS

The Fischer Tropsch reaction, using a simulated gas mixture similar to that obtained from biomass transformation (biosyngas), was studied over Fe/SiO2catalysts. The reaction was carried out in a stainless steel fixed bed reactor at 300 °C and 1 MPa. Excess solvent impregnation was used to prepare th...

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Autores principales:	UBILLA,P, GARCÍA,R, FIERRO,J.L.G, ESCALONA,N
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2010
Materias:	Fischer Tropsch synthesis biosyngas Fe/SiO2 catalysts biomass
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100009
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spelling	oai:scielo:S0717-970720100001000092010-04-29HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTSUBILLA,PGARCÍA,RFIERRO,J.L.GESCALONA,N Fischer Tropsch synthesis biosyngas Fe/SiO2 catalysts biomass The Fischer Tropsch reaction, using a simulated gas mixture similar to that obtained from biomass transformation (biosyngas), was studied over Fe/SiO2catalysts. The reaction was carried out in a stainless steel fixed bed reactor at 300 °C and 1 MPa. Excess solvent impregnation was used to prepare the catalysts. Nitrogen adsorption at -196 °C, thermal programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) were used as characterization methods. The highest CO conversion was obtained for the catalyst with Fe-loading of 15wt% whereas it decreased at higher Fe loadings. The decrease ofthe activity is explained in terms ofthe drop ofthe active sites due to the formation of large Femetallic aggregates. The Fe/SiO2 catalysts presented a wide distribution of liquid hydrocarbons (C6 to C 18) and high methane formation. The liquid product distribution was related to the average size of iron particles. The increase of iron particle size favours the formation of hydrocarbons centred in C 11-14 chain length.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.55 n.1 20102010-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100009en10.4067/S0717-97072010000100009
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Fischer Tropsch synthesis biosyngas Fe/SiO2 catalysts biomass
spellingShingle	Fischer Tropsch synthesis biosyngas Fe/SiO2 catalysts biomass UBILLA,P GARCÍA,R FIERRO,J.L.G ESCALONA,N HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS
description	The Fischer Tropsch reaction, using a simulated gas mixture similar to that obtained from biomass transformation (biosyngas), was studied over Fe/SiO2catalysts. The reaction was carried out in a stainless steel fixed bed reactor at 300 °C and 1 MPa. Excess solvent impregnation was used to prepare the catalysts. Nitrogen adsorption at -196 °C, thermal programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) were used as characterization methods. The highest CO conversion was obtained for the catalyst with Fe-loading of 15wt% whereas it decreased at higher Fe loadings. The decrease ofthe activity is explained in terms ofthe drop ofthe active sites due to the formation of large Femetallic aggregates. The Fe/SiO2 catalysts presented a wide distribution of liquid hydrocarbons (C6 to C 18) and high methane formation. The liquid product distribution was related to the average size of iron particles. The increase of iron particle size favours the formation of hydrocarbons centred in C 11-14 chain length.
author	UBILLA,P GARCÍA,R FIERRO,J.L.G ESCALONA,N
author_facet	UBILLA,P GARCÍA,R FIERRO,J.L.G ESCALONA,N
author_sort	UBILLA,P
title	HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS
title_short	HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS
title_full	HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS
title_fullStr	HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS
title_full_unstemmed	HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS
title_sort	hydrocarbons synthesis from a simulated biosyngas feed over fe/sio2, catalysts
publisher	Sociedad Chilena de Química
publishDate	2010
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100009
work_keys_str_mv	AT ubillap hydrocarbonssynthesisfromasimulatedbiosyngasfeedoverfesio2catalysts AT garciar hydrocarbonssynthesisfromasimulatedbiosyngasfeedoverfesio2catalysts AT fierrojlg hydrocarbonssynthesisfromasimulatedbiosyngasfeedoverfesio2catalysts AT escalonan hydrocarbonssynthesisfromasimulatedbiosyngasfeedoverfesio2catalysts
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HYDROCARBONS SYNTHESIS FROM A SIMULATED BIOSYNGAS FEED OVER FE/SIO2, CATALYSTS

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