ONLINE MULTI-STAGE MEMBRANE FILTRATION OF SYNTHETIC POLYDISPERSED WATER-SOLUBLE POLYMERS WITH UV VISIBLE ABSORPTION AS A MODE FOR THEIR DETECTION

This paper reports the application of online membrane filtration with UV visible absorption as a mode of polydispersed substances detection for poly(acryloyl morpholine-co-2-acrylamido-2-methyl-1-propane sulfonic acid), poly[2-acrylamido-2-methyl-1-propane sulfonic acid-co-(3-acryloylamidopropyl) tr...

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Autores principales: RIVAS,B.L, SHKINEV,V.M, DZHERAJAN,T.G, DANILOVA,T.V, PEREIRA,E.D, MAUREIRA,A
Lenguaje:English
Publicado: Sociedad Chilena de Química 2010
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100013
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Sumario:This paper reports the application of online membrane filtration with UV visible absorption as a mode of polydispersed substances detection for poly(acryloyl morpholine-co-2-acrylamido-2-methyl-1-propane sulfonic acid), poly[2-acrylamido-2-methyl-1-propane sulfonic acid-co-(3-acryloylamidopropyl) trimethylammonium nitrate), and poly(vinyl alcohol-co-crotonic acid) 10 % of crotonic acid which can be used in medicine and technology. The mass balance in all the cases was not below 100 ± 7 %. The calibration curve are linear at 1opt , 245, 230, and 220 nm in the interval 0.1-4.0 mg/mL, 0.2-3.0 mg/mL and 0.2-6.0 mg/mL, respectively. It was also used the combination of microfiltration, MF, and gel permeation chromatography, GPC to provide more complete information about the molecular weight distribution of the obtained fractions.