AN INEXPENSIVE AND CONVENIENT PROCEDURE FOR CHLOROMETHYLATION OF AROMATIC HYDROCARBONS BY PHASE TRANSFER CATALYSIS IN AQUEOUS MEDIA

Reaction of aromatic hydrocarbons catalyzed by a novel catalytic system consisting of zinc chloride, acetic acid, sulfuric acid and PEG-800 in aqueous media under PTC conditions results in chloromethylation in good to excellent yield.

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Detalles Bibliográficos
Autores principales: HU,YU LIN, LU,MING, GE,QIANG, CHENG WANG,PENG, ZHANG,SHENG BIN, LU,TING TING
Lenguaje:English
Publicado: Sociedad Chilena de Química 2010
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100023
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Descripción
Sumario:Reaction of aromatic hydrocarbons catalyzed by a novel catalytic system consisting of zinc chloride, acetic acid, sulfuric acid and PEG-800 in aqueous media under PTC conditions results in chloromethylation in good to excellent yield.