ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values...
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| Autores principales: | , , |
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| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2010
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| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100035 |
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| Sumario: | The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values of surface converge. Maximum value of surface converge was 0.998 for BTA at 35 °C and 15 g/1 inhibitor concentration, while the lower value was 0.868 at 55 °C and 1 g/1 inhibitor concentration. The films formed on the copper-nickel alloy surface of BTA appeared to obey the Langmuir Adsorption Isotherm more than Freundlich adsorption isotherm. In the other hand, results showed that the Kinetic-Thermodynamic Model was unsuitable to fit the experimental data of the BTA of the present study. |
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