ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID

The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values...

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Autores principales: KHADOM,ANEES A, YARO,APRAEL S, KADHUM,ABDUL AMIR H
Lenguaje:English
Publicado: Sociedad Chilena de Química 2010
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100035
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spelling oai:scielo:S0717-970720100001000352010-04-29ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACIDKHADOM,ANEES AYARO,APRAEL SKADHUM,ABDUL AMIR H adsorption isotherms corrosion inhibition copper-nickel alloy benzotriazole inhibitor efficiency The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values of surface converge. Maximum value of surface converge was 0.998 for BTA at 35 °C and 15 g/1 inhibitor concentration, while the lower value was 0.868 at 55 °C and 1 g/1 inhibitor concentration. The films formed on the copper-nickel alloy surface of BTA appeared to obey the Langmuir Adsorption Isotherm more than Freundlich adsorption isotherm. In the other hand, results showed that the Kinetic-Thermodynamic Model was unsuitable to fit the experimental data of the BTA of the present study.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.55 n.1 20102010-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100035en10.4067/S0717-97072010000100035
institution Scielo Chile
collection Scielo Chile
language English
topic adsorption isotherms
corrosion inhibition
copper-nickel alloy
benzotriazole
inhibitor efficiency
spellingShingle adsorption isotherms
corrosion inhibition
copper-nickel alloy
benzotriazole
inhibitor efficiency
KHADOM,ANEES A
YARO,APRAEL S
KADHUM,ABDUL AMIR H
ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
description The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values of surface converge. Maximum value of surface converge was 0.998 for BTA at 35 °C and 15 g/1 inhibitor concentration, while the lower value was 0.868 at 55 °C and 1 g/1 inhibitor concentration. The films formed on the copper-nickel alloy surface of BTA appeared to obey the Langmuir Adsorption Isotherm more than Freundlich adsorption isotherm. In the other hand, results showed that the Kinetic-Thermodynamic Model was unsuitable to fit the experimental data of the BTA of the present study.
author KHADOM,ANEES A
YARO,APRAEL S
KADHUM,ABDUL AMIR H
author_facet KHADOM,ANEES A
YARO,APRAEL S
KADHUM,ABDUL AMIR H
author_sort KHADOM,ANEES A
title ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
title_short ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
title_full ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
title_fullStr ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
title_full_unstemmed ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
title_sort adsorption mechanism of benzotriazole for corrosion inhibition of copper-nickel alloy in hydrochloric acid
publisher Sociedad Chilena de Química
publishDate 2010
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100035
work_keys_str_mv AT khadomaneesa adsorptionmechanismofbenzotriazoleforcorrosioninhibitionofcoppernickelalloyinhydrochloricacid
AT yaroapraels adsorptionmechanismofbenzotriazoleforcorrosioninhibitionofcoppernickelalloyinhydrochloricacid
AT kadhumabdulamirh adsorptionmechanismofbenzotriazoleforcorrosioninhibitionofcoppernickelalloyinhydrochloricacid
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