ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values...
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Sociedad Chilena de Química
2010
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oai:scielo:S0717-970720100001000352010-04-29ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACIDKHADOM,ANEES AYARO,APRAEL SKADHUM,ABDUL AMIR H adsorption isotherms corrosion inhibition copper-nickel alloy benzotriazole inhibitor efficiency The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values of surface converge. Maximum value of surface converge was 0.998 for BTA at 35 °C and 15 g/1 inhibitor concentration, while the lower value was 0.868 at 55 °C and 1 g/1 inhibitor concentration. The films formed on the copper-nickel alloy surface of BTA appeared to obey the Langmuir Adsorption Isotherm more than Freundlich adsorption isotherm. In the other hand, results showed that the Kinetic-Thermodynamic Model was unsuitable to fit the experimental data of the BTA of the present study.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.55 n.1 20102010-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100035en10.4067/S0717-97072010000100035 |
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adsorption isotherms corrosion inhibition copper-nickel alloy benzotriazole inhibitor efficiency |
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adsorption isotherms corrosion inhibition copper-nickel alloy benzotriazole inhibitor efficiency KHADOM,ANEES A YARO,APRAEL S KADHUM,ABDUL AMIR H ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID |
description |
The inhibition of copper corrosion by Benzotriazole (BTA) in 5% HC1 has been investigated by weight loss technique at different temperatures. Langmuir adsorption isotherm, Freundlich Adsorption Isotherm and Kinetic-Thermodynamic Model were used to describe the adsorption process depending on values of surface converge. Maximum value of surface converge was 0.998 for BTA at 35 °C and 15 g/1 inhibitor concentration, while the lower value was 0.868 at 55 °C and 1 g/1 inhibitor concentration. The films formed on the copper-nickel alloy surface of BTA appeared to obey the Langmuir Adsorption Isotherm more than Freundlich adsorption isotherm. In the other hand, results showed that the Kinetic-Thermodynamic Model was unsuitable to fit the experimental data of the BTA of the present study. |
author |
KHADOM,ANEES A YARO,APRAEL S KADHUM,ABDUL AMIR H |
author_facet |
KHADOM,ANEES A YARO,APRAEL S KADHUM,ABDUL AMIR H |
author_sort |
KHADOM,ANEES A |
title |
ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID |
title_short |
ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID |
title_full |
ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID |
title_fullStr |
ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID |
title_full_unstemmed |
ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID |
title_sort |
adsorption mechanism of benzotriazole for corrosion inhibition of copper-nickel alloy in hydrochloric acid |
publisher |
Sociedad Chilena de Química |
publishDate |
2010 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100035 |
work_keys_str_mv |
AT khadomaneesa adsorptionmechanismofbenzotriazoleforcorrosioninhibitionofcoppernickelalloyinhydrochloricacid AT yaroapraels adsorptionmechanismofbenzotriazoleforcorrosioninhibitionofcoppernickelalloyinhydrochloricacid AT kadhumabdulamirh adsorptionmechanismofbenzotriazoleforcorrosioninhibitionofcoppernickelalloyinhydrochloricacid |
_version_ |
1718445424049651712 |