SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE
In present work we report the synthesis of five complexes of three different formulations, viz. [cis-RuCl2(SBANTP)2]; [trans-RuCl2(SBANTP)2]; and [RuCl4(SBANTP)-][X]+; where [X]+ = [(dmso)2H]+, Na+ or [(tmso)H]+and SBANTP = 4-(benzyideneamino)-1,5-dimethyl-2-phenyl-l,2-dihydropyrazole-3-one, from di...
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| Lenguaje: | English |
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Sociedad Chilena de Química
2010
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oai:scielo:S0717-970720100002000032010-09-06SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASESHUKLA,SATYENDRA NGAUR,PRATIKSHAPRASAD,MAHENDERAGARWAL,KAVITAKAUR,HARPREETSETUA,DEEPAK KMEHROTRA,RIPULPRASAD,MAMTASRIVASTAVA,RADHEY S Dimethylsulphoxide Tetramethylenesulphoxide Ruthenium Schiff base In present work we report the synthesis of five complexes of three different formulations, viz. [cis-RuCl2(SBANTP)2]; [trans-RuCl2(SBANTP)2]; and [RuCl4(SBANTP)-][X]+; where [X]+ = [(dmso)2H]+, Na+ or [(tmso)H]+and SBANTP = 4-(benzyideneamino)-1,5-dimethyl-2-phenyl-l,2-dihydropyrazole-3-one, from different routes. The complexes were characterized on the basis of elemental analyses, molar conductance measurements, magnetic susceptibility, electronic spectra, FTIR, ¹H-NMR,13C{¹H}NMR spectroscopy, FAB-Mass spectrometry. Complex 2 was also analyzed by EDX analysis.The 3D molecular modeling and analysis for bond length and bond angle have been also carried out for one of the representative complex 1. AU the five complexes were screened for antibacterial activity and found to be more potent against gram negative bacteria Escherichia coli than their precursora but less active than chloramphenicol.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.55 n.2 20102010-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000200003en10.4067/S0717-97072010000200003 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
Dimethylsulphoxide Tetramethylenesulphoxide Ruthenium Schiff base |
| spellingShingle |
Dimethylsulphoxide Tetramethylenesulphoxide Ruthenium Schiff base SHUKLA,SATYENDRA N GAUR,PRATIKSHA PRASAD,MAHENDER AGARWAL,KAVITA KAUR,HARPREET SETUA,DEEPAK K MEHROTRA,RIPUL PRASAD,MAMTA SRIVASTAVA,RADHEY S SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE |
| description |
In present work we report the synthesis of five complexes of three different formulations, viz. [cis-RuCl2(SBANTP)2]; [trans-RuCl2(SBANTP)2]; and [RuCl4(SBANTP)-][X]+; where [X]+ = [(dmso)2H]+, Na+ or [(tmso)H]+and SBANTP = 4-(benzyideneamino)-1,5-dimethyl-2-phenyl-l,2-dihydropyrazole-3-one, from different routes. The complexes were characterized on the basis of elemental analyses, molar conductance measurements, magnetic susceptibility, electronic spectra, FTIR, ¹H-NMR,13C{¹H}NMR spectroscopy, FAB-Mass spectrometry. Complex 2 was also analyzed by EDX analysis.The 3D molecular modeling and analysis for bond length and bond angle have been also carried out for one of the representative complex 1. AU the five complexes were screened for antibacterial activity and found to be more potent against gram negative bacteria Escherichia coli than their precursora but less active than chloramphenicol. |
| author |
SHUKLA,SATYENDRA N GAUR,PRATIKSHA PRASAD,MAHENDER AGARWAL,KAVITA KAUR,HARPREET SETUA,DEEPAK K MEHROTRA,RIPUL PRASAD,MAMTA SRIVASTAVA,RADHEY S |
| author_facet |
SHUKLA,SATYENDRA N GAUR,PRATIKSHA PRASAD,MAHENDER AGARWAL,KAVITA KAUR,HARPREET SETUA,DEEPAK K MEHROTRA,RIPUL PRASAD,MAMTA SRIVASTAVA,RADHEY S |
| author_sort |
SHUKLA,SATYENDRA N |
| title |
SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE |
| title_short |
SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE |
| title_full |
SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE |
| title_fullStr |
SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE |
| title_full_unstemmed |
SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SOME CHLOROSULPHOXIDE RUTHENIUM (II) AND RUTHENIUM (III) COMPLEXES OF 4-(BENZYLIDENEAMINO)-1,2-DIMETHYL-2-PHENYL-1,2-DIHYDROPYRAZOLE-3-ONE, SCHIFF BASE |
| title_sort |
synthesis, spectroscopic characterization and antibacterial activity of some chlorosulphoxide ruthenium (ii) and ruthenium (iii) complexes of 4-(benzylideneamino)-1,2-dimethyl-2-phenyl-1,2-dihydropyrazole-3-one, schiff base |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2010 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000200003 |
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