COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER

1-furoyl-3,3-diethylthiourea was used as a novel neutral carrier in ion selective electrode for copperII detection and determination. The Cu2+ selective plasticized polyvinyl chloride (PVC) membrane electrode exhibited reversible potential responses with Nernstian slope of 29.34± 0.6 mV/decade for C...

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Autores principales: ARADA PÉREZ,M. DE LOS A, LANDAZURY YANES,SANTIAGO, CARDONA,M, AGUILERA,L, YAZDANI-PEDRAM,M
Lenguaje:English
Publicado: Sociedad Chilena de Química 2010
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000300022
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spelling oai:scielo:S0717-970720100003000222011-01-25COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIERARADA PÉREZ,M. DE LOS ALANDAZURY YANES,SANTIAGOCARDONA,MAGUILERA,LYAZDANI-PEDRAM,M Neutral carrier CopperII-selective potentiometric sensor Ion-selective electrode (ISE) 1-furoyl-3,3-diethylthiourea was used as a novel neutral carrier in ion selective electrode for copperII detection and determination. The Cu2+ selective plasticized polyvinyl chloride (PVC) membrane electrode exhibited reversible potential responses with Nernstian slope of 29.34± 0.6 mV/decade for Cu2+ ions in the concentration range from 1.0x10-7 to 1.0x10-2 mol/dm³ with a practical detection limit (PDL) of 3.84x10-7 and lower limit of linear response (LLLR) of 6.15x10-7 mol/dm³ and alife-time of 20 days. The response time, pH effect and other characteristics of the electrodes were also studied.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.55 n.3 20102010-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000300022en10.4067/S0717-97072010000300022
institution Scielo Chile
collection Scielo Chile
language English
topic Neutral carrier
CopperII-selective potentiometric sensor
Ion-selective electrode (ISE)
spellingShingle Neutral carrier
CopperII-selective potentiometric sensor
Ion-selective electrode (ISE)
ARADA PÉREZ,M. DE LOS A
LANDAZURY YANES,SANTIAGO
CARDONA,M
AGUILERA,L
YAZDANI-PEDRAM,M
COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER
description 1-furoyl-3,3-diethylthiourea was used as a novel neutral carrier in ion selective electrode for copperII detection and determination. The Cu2+ selective plasticized polyvinyl chloride (PVC) membrane electrode exhibited reversible potential responses with Nernstian slope of 29.34± 0.6 mV/decade for Cu2+ ions in the concentration range from 1.0x10-7 to 1.0x10-2 mol/dm³ with a practical detection limit (PDL) of 3.84x10-7 and lower limit of linear response (LLLR) of 6.15x10-7 mol/dm³ and alife-time of 20 days. The response time, pH effect and other characteristics of the electrodes were also studied.
author ARADA PÉREZ,M. DE LOS A
LANDAZURY YANES,SANTIAGO
CARDONA,M
AGUILERA,L
YAZDANI-PEDRAM,M
author_facet ARADA PÉREZ,M. DE LOS A
LANDAZURY YANES,SANTIAGO
CARDONA,M
AGUILERA,L
YAZDANI-PEDRAM,M
author_sort ARADA PÉREZ,M. DE LOS A
title COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER
title_short COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER
title_full COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER
title_fullStr COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER
title_full_unstemmed COPPERII-SELECTIVE ELECTRODES BASED ON 1-FUROYL-3,3-DIETHYLTHIOUREA AS A NEUTRAL CARRIER
title_sort copperii-selective electrodes based on 1-furoyl-3,3-diethylthiourea as a neutral carrier
publisher Sociedad Chilena de Química
publishDate 2010
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000300022
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