LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT

Extraction behaviour of Ce(IV) from salicylate medium has been studied with the using N-n-octylaniline in xylene as an extractant. Cerium(IV) was completely recovered from the organic phase using 2.0 M hydrochloric acid and determined spectrophotometrically as complex with Arsenazo III. The influenc...

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Autores principales:	KOKARE,B. N, MANDHARE,A. M, ANUSE,M. A
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2010
Materias:	Solvent extraction Ce(IV) N-n-octylaniline sodium salicylate
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000400004
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spelling	oai:scielo:S0717-970720100004000042011-05-25LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANTKOKARE,B. NMANDHARE,A. MANUSE,M. A Solvent extraction Ce(IV) N-n-octylaniline sodium salicylate Extraction behaviour of Ce(IV) from salicylate medium has been studied with the using N-n-octylaniline in xylene as an extractant. Cerium(IV) was completely recovered from the organic phase using 2.0 M hydrochloric acid and determined spectrophotometrically as complex with Arsenazo III. The influence of equilibrium pH, extractant concentration, stripping agents, equilibration time, nature of diluents, and diverse ions on the extraction of Ce(IV) was investigated. The stoichiometry of the extracted species was determined on the basis of slope analysis. The separation of Ce(IV) was carried out from some associated metals like U(VI), Th(IV), La(III), Y(III), Zr(IV), Nb(V), Gd(III) and Nd(III). The method presented is simple, reproducible, rapid and has been successfully applied for the determination of Ce(IV) in synthetic mixture, semiconductor films and monazite sand.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.55 n.4 20102010-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000400004en10.4067/S0717-97072010000400004
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Solvent extraction Ce(IV) N-n-octylaniline sodium salicylate
spellingShingle	Solvent extraction Ce(IV) N-n-octylaniline sodium salicylate KOKARE,B. N MANDHARE,A. M ANUSE,M. A LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT
description	Extraction behaviour of Ce(IV) from salicylate medium has been studied with the using N-n-octylaniline in xylene as an extractant. Cerium(IV) was completely recovered from the organic phase using 2.0 M hydrochloric acid and determined spectrophotometrically as complex with Arsenazo III. The influence of equilibrium pH, extractant concentration, stripping agents, equilibration time, nature of diluents, and diverse ions on the extraction of Ce(IV) was investigated. The stoichiometry of the extracted species was determined on the basis of slope analysis. The separation of Ce(IV) was carried out from some associated metals like U(VI), Th(IV), La(III), Y(III), Zr(IV), Nb(V), Gd(III) and Nd(III). The method presented is simple, reproducible, rapid and has been successfully applied for the determination of Ce(IV) in synthetic mixture, semiconductor films and monazite sand.
author	KOKARE,B. N MANDHARE,A. M ANUSE,M. A
author_facet	KOKARE,B. N MANDHARE,A. M ANUSE,M. A
author_sort	KOKARE,B. N
title	LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT
title_short	LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT
title_full	LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT
title_fullStr	LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT
title_full_unstemmed	LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT
title_sort	liquid - liquid extraction of cerium(iv) from salicylate media using n-7v-octylaniline in xylene as an extractant
publisher	Sociedad Chilena de Química
publishDate	2010
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000400004
work_keys_str_mv	AT kokarebn liquidliquidextractionofceriumivfromsalicylatemediausingn7voctylanilineinxyleneasanextractant AT mandhaream liquidliquidextractionofceriumivfromsalicylatemediausingn7voctylanilineinxyleneasanextractant AT anusema liquidliquidextractionofceriumivfromsalicylatemediausingn7voctylanilineinxyleneasanextractant
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LIQUID - LIQUID EXTRACTION OF CERIUM(IV) FROM SALICYLATE MEDIA USING N-7V-OCTYLANILINE IN XYLENE AS AN EXTRACTANT

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