SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES

Iron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimi...

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Autores principales: DAHROUCH,MOHAMED, DÍAZ,ENZO, ITURRA,ANDRÉS, PARRA,MARIA, GATICA,NICOLÁS, MORENO,YANKO, CHÁVEZ,IVONNE, MANRÍQUEZ,JUAN MANUEL
Lenguaje:English
Publicado: Sociedad Chilena de Química 2011
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000100014
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spelling oai:scielo:S0717-970720110001000142011-06-17SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURESDAHROUCH,MOHAMEDDÍAZ,ENZOITURRA,ANDRÉSPARRA,MARIAGATICA,NICOLÁSMORENO,YANKOCHÁVEZ,IVONNEMANRÍQUEZ,JUAN MANUELIron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimide materials based on s-indacene ligand has shown a clear electronic delocalization observed by IR spectroscopy. The thermal degradation of these materials studied by thermogravimetric analyses (TGA), starts around 180-200°C.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.1 20112011-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000100014en10.4067/S0717-97072011000100014
institution Scielo Chile
collection Scielo Chile
language English
description Iron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimide materials based on s-indacene ligand has shown a clear electronic delocalization observed by IR spectroscopy. The thermal degradation of these materials studied by thermogravimetric analyses (TGA), starts around 180-200°C.
author DAHROUCH,MOHAMED
DÍAZ,ENZO
ITURRA,ANDRÉS
PARRA,MARIA
GATICA,NICOLÁS
MORENO,YANKO
CHÁVEZ,IVONNE
MANRÍQUEZ,JUAN MANUEL
spellingShingle DAHROUCH,MOHAMED
DÍAZ,ENZO
ITURRA,ANDRÉS
PARRA,MARIA
GATICA,NICOLÁS
MORENO,YANKO
CHÁVEZ,IVONNE
MANRÍQUEZ,JUAN MANUEL
SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
author_facet DAHROUCH,MOHAMED
DÍAZ,ENZO
ITURRA,ANDRÉS
PARRA,MARIA
GATICA,NICOLÁS
MORENO,YANKO
CHÁVEZ,IVONNE
MANRÍQUEZ,JUAN MANUEL
author_sort DAHROUCH,MOHAMED
title SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
title_short SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
title_full SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
title_fullStr SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
title_full_unstemmed SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
title_sort synthesis, characterization and thermal properties of iron material including carbodiimide and s-indacene structures
publisher Sociedad Chilena de Química
publishDate 2011
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000100014
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