SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES
Iron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimi...
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Sociedad Chilena de Química
2011
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Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000100014 |
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oai:scielo:S0717-970720110001000142011-06-17SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURESDAHROUCH,MOHAMEDDÍAZ,ENZOITURRA,ANDRÉSPARRA,MARIAGATICA,NICOLÁSMORENO,YANKOCHÁVEZ,IVONNEMANRÍQUEZ,JUAN MANUELIron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimide materials based on s-indacene ligand has shown a clear electronic delocalization observed by IR spectroscopy. The thermal degradation of these materials studied by thermogravimetric analyses (TGA), starts around 180-200°C.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.1 20112011-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000100014en10.4067/S0717-97072011000100014 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
description |
Iron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimide materials based on s-indacene ligand has shown a clear electronic delocalization observed by IR spectroscopy. The thermal degradation of these materials studied by thermogravimetric analyses (TGA), starts around 180-200°C. |
author |
DAHROUCH,MOHAMED DÍAZ,ENZO ITURRA,ANDRÉS PARRA,MARIA GATICA,NICOLÁS MORENO,YANKO CHÁVEZ,IVONNE MANRÍQUEZ,JUAN MANUEL |
spellingShingle |
DAHROUCH,MOHAMED DÍAZ,ENZO ITURRA,ANDRÉS PARRA,MARIA GATICA,NICOLÁS MORENO,YANKO CHÁVEZ,IVONNE MANRÍQUEZ,JUAN MANUEL SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES |
author_facet |
DAHROUCH,MOHAMED DÍAZ,ENZO ITURRA,ANDRÉS PARRA,MARIA GATICA,NICOLÁS MORENO,YANKO CHÁVEZ,IVONNE MANRÍQUEZ,JUAN MANUEL |
author_sort |
DAHROUCH,MOHAMED |
title |
SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES |
title_short |
SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES |
title_full |
SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES |
title_fullStr |
SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES |
title_full_unstemmed |
SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTIES OF IRON MATERIAL INCLUDING CARBODIIMIDE AND S-INDACENE STRUCTURES |
title_sort |
synthesis, characterization and thermal properties of iron material including carbodiimide and s-indacene structures |
publisher |
Sociedad Chilena de Química |
publishDate |
2011 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000100014 |
work_keys_str_mv |
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