COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS
In this work we studied the cobalt electrodeposition onto a stainless steel 304 electrode from an aqueous solution containing 10¹ M of CoSO4 + 1M (NH4)2SO4 at natural pH of 4.5. Black cobalt deposits were obtained under our experimental conditions. The average diffusion coefficient calculated was 9....
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| Lenguaje: | English |
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Sociedad Chilena de Química
2011
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oai:scielo:S0717-970720110002000012011-09-01COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONSRAMOS-LORA,NANCYMENDOZA-HUIZAR,L.HRIOS REYES,C.H Black cobalt SSE 304 electrodeposition kinetic In this work we studied the cobalt electrodeposition onto a stainless steel 304 electrode from an aqueous solution containing 10¹ M of CoSO4 + 1M (NH4)2SO4 at natural pH of 4.5. Black cobalt deposits were obtained under our experimental conditions. The average diffusion coefficient calculated was 9.8X10(6) cm²s-1 while the AG for the formation of stable nucleus was 1.013X10(20) J/nuclei. The critical cluster's size calculated was 0 which suggested that each active site is a critical nucleus on the SSE-304 surface. The Scanning Electron Microscopy images showed the formation of non-uniform cobalt particles.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.2 20112011-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200001en10.4067/S0717-97072011000200001 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
Black cobalt SSE 304 electrodeposition kinetic |
| spellingShingle |
Black cobalt SSE 304 electrodeposition kinetic RAMOS-LORA,NANCY MENDOZA-HUIZAR,L.H RIOS REYES,C.H COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS |
| description |
In this work we studied the cobalt electrodeposition onto a stainless steel 304 electrode from an aqueous solution containing 10¹ M of CoSO4 + 1M (NH4)2SO4 at natural pH of 4.5. Black cobalt deposits were obtained under our experimental conditions. The average diffusion coefficient calculated was 9.8X10(6) cm²s-1 while the AG for the formation of stable nucleus was 1.013X10(20) J/nuclei. The critical cluster's size calculated was 0 which suggested that each active site is a critical nucleus on the SSE-304 surface. The Scanning Electron Microscopy images showed the formation of non-uniform cobalt particles. |
| author |
RAMOS-LORA,NANCY MENDOZA-HUIZAR,L.H RIOS REYES,C.H |
| author_facet |
RAMOS-LORA,NANCY MENDOZA-HUIZAR,L.H RIOS REYES,C.H |
| author_sort |
RAMOS-LORA,NANCY |
| title |
COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS |
| title_short |
COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS |
| title_full |
COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS |
| title_fullStr |
COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS |
| title_full_unstemmed |
COBALT ELECTRODEPOSITION ONTO STAINLESS STEEL 304 FROM AMMONIACAL SOLUTIONS |
| title_sort |
cobalt electrodeposition onto stainless steel 304 from ammoniacal solutions |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2011 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200001 |
| work_keys_str_mv |
AT ramosloranancy cobaltelectrodepositionontostainlesssteel304fromammoniacalsolutions AT mendozahuizarlh cobaltelectrodepositionontostainlesssteel304fromammoniacalsolutions AT riosreyesch cobaltelectrodepositionontostainlesssteel304fromammoniacalsolutions |
| _version_ |
1718445444614324224 |