ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER

A simple and convenient one-pot procedure is reported for the synthesis of 1,2-diketones from corresponding benzoin-type condensation reaction of aromatic aldehydes in water with N,N-dialkylbenzimidazolium salt as condensation catalyst and air as oxidizing reagent.

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Autores principales: BI,XIAOXIN, WU,LINTAO, YAN,CHAOGUO, JING,XIAOBI, ZHU,HONGXIANG
Lenguaje:English
Publicado: Sociedad Chilena de Química 2011
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200008
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spelling oai:scielo:S0717-970720110002000082011-09-01ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATERBI,XIAOXINWU,LINTAOYAN,CHAOGUOJING,XIAOBIZHU,HONGXIANG benzils benzoin condensation benzimidazolium salts metal-free oxidation A simple and convenient one-pot procedure is reported for the synthesis of 1,2-diketones from corresponding benzoin-type condensation reaction of aromatic aldehydes in water with N,N-dialkylbenzimidazolium salt as condensation catalyst and air as oxidizing reagent.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.2 20112011-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200008en10.4067/S0717-97072011000200008
institution Scielo Chile
collection Scielo Chile
language English
topic benzils
benzoin condensation
benzimidazolium salts
metal-free oxidation
spellingShingle benzils
benzoin condensation
benzimidazolium salts
metal-free oxidation
BI,XIAOXIN
WU,LINTAO
YAN,CHAOGUO
JING,XIAOBI
ZHU,HONGXIANG
ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER
description A simple and convenient one-pot procedure is reported for the synthesis of 1,2-diketones from corresponding benzoin-type condensation reaction of aromatic aldehydes in water with N,N-dialkylbenzimidazolium salt as condensation catalyst and air as oxidizing reagent.
author BI,XIAOXIN
WU,LINTAO
YAN,CHAOGUO
JING,XIAOBI
ZHU,HONGXIANG
author_facet BI,XIAOXIN
WU,LINTAO
YAN,CHAOGUO
JING,XIAOBI
ZHU,HONGXIANG
author_sort BI,XIAOXIN
title ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER
title_short ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER
title_full ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER
title_fullStr ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER
title_full_unstemmed ONE-POT SYNTHESIS BENZILS FROM ALDEHYDES VIA NHC-CATALYZED BENZOIN DIMERIZATION UNDER METAL-FREE CONDITIONS IN WATER
title_sort one-pot synthesis benzils from aldehydes via nhc-catalyzed benzoin dimerization under metal-free conditions in water
publisher Sociedad Chilena de Química
publishDate 2011
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200008
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AT wulintao onepotsynthesisbenzilsfromaldehydesvianhccatalyzedbenzoindimerizationundermetalfreeconditionsinwater
AT yanchaoguo onepotsynthesisbenzilsfromaldehydesvianhccatalyzedbenzoindimerizationundermetalfreeconditionsinwater
AT jingxiaobi onepotsynthesisbenzilsfromaldehydesvianhccatalyzedbenzoindimerizationundermetalfreeconditionsinwater
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