ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES

The silylant 3-cloropropyltriethoxysilyl was anchored over silica gel in anhydrous conditions in order to react with thiourea to obtain modified silica gel with thiouronium. The aim to obtain an inorganic support that is able to hijack metals from the VIII group such as palladium. The product was ch...

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Autores principales:	CARREÑO G,ALEXANDER, SCHOTT V,EDUARDO, ZÁRATE B,XIMENA, ARRATIA-PEREZ,RAMIRO, VEGA DE K,JUAN CARLOS, MARDONES L,MIGUEL, MANRÍQUEZ,JUAN M, CHÁVEZ M,IVONNE
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2011
Materias:	silica gel functionalization coordination agents
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200015
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spelling	oai:scielo:S0717-970720110002000152011-09-01ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIESCARREÑO G,ALEXANDERSCHOTT V,EDUARDOZÁRATE B,XIMENAARRATIA-PEREZ,RAMIROVEGA DE K,JUAN CARLOSMARDONES L,MIGUELMANRÍQUEZ,JUAN MCHÁVEZ M,IVONNE silica gel functionalization coordination agents The silylant 3-cloropropyltriethoxysilyl was anchored over silica gel in anhydrous conditions in order to react with thiourea to obtain modified silica gel with thiouronium. The aim to obtain an inorganic support that is able to hijack metals from the VIII group such as palladium. The product was characterized by Sbet and FTIR infrared spectroscopy. For the determination of the structure in the modified silica gel NMR spectra of silicon and carbon were preformed in solid state. The coordination form of the modified silica gel to the metal was studied computationally in the context of the DFT theory, using the ADF code. This was a collaborative work with "Fundación Chile" for the recuperation of precious metals from the mining industry.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.2 20112011-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200015en10.4067/S0717-97072011000200015
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	silica gel functionalization coordination agents
spellingShingle	silica gel functionalization coordination agents CARREÑO G,ALEXANDER SCHOTT V,EDUARDO ZÁRATE B,XIMENA ARRATIA-PEREZ,RAMIRO VEGA DE K,JUAN CARLOS MARDONES L,MIGUEL MANRÍQUEZ,JUAN M CHÁVEZ M,IVONNE ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES
description	The silylant 3-cloropropyltriethoxysilyl was anchored over silica gel in anhydrous conditions in order to react with thiourea to obtain modified silica gel with thiouronium. The aim to obtain an inorganic support that is able to hijack metals from the VIII group such as palladium. The product was characterized by Sbet and FTIR infrared spectroscopy. For the determination of the structure in the modified silica gel NMR spectra of silicon and carbon were preformed in solid state. The coordination form of the modified silica gel to the metal was studied computationally in the context of the DFT theory, using the ADF code. This was a collaborative work with "Fundación Chile" for the recuperation of precious metals from the mining industry.
author	CARREÑO G,ALEXANDER SCHOTT V,EDUARDO ZÁRATE B,XIMENA ARRATIA-PEREZ,RAMIRO VEGA DE K,JUAN CARLOS MARDONES L,MIGUEL MANRÍQUEZ,JUAN M CHÁVEZ M,IVONNE
author_facet	CARREÑO G,ALEXANDER SCHOTT V,EDUARDO ZÁRATE B,XIMENA ARRATIA-PEREZ,RAMIRO VEGA DE K,JUAN CARLOS MARDONES L,MIGUEL MANRÍQUEZ,JUAN M CHÁVEZ M,IVONNE
author_sort	CARREÑO G,ALEXANDER
title	ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES
title_short	ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES
title_full	ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES
title_fullStr	ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES
title_full_unstemmed	ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES
title_sort	adsorption essays of palladium in modified silica gel with thiouronium groups: experimental and theorical studies
publisher	Sociedad Chilena de Química
publishDate	2011
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000200015
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ADSORPTION ESSAYS OF PALLADIUM IN MODIFIED SILICA GEL WITH THIOURONIUM GROUPS: EXPERIMENTAL AND THEORICAL STUDIES

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