STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]

STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]

We have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br] by direct reaction of (Re(CO)3Br(THF))2 and the ligand (C6H5)2(C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rheni...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: VENEGAS,FELIPE, PIZARRO,NANCY, VEGA,ANDRES
Lenguaje:English
Publicado: Sociedad Chilena de Química 2011
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000300023
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:scielo:S0717-97072011000300023
record_format dspace
spelling oai:scielo:S0717-970720110003000232012-01-11STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]VENEGAS,FELIPEPIZARRO,NANCYVEGA,ANDRESWe have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br] by direct reaction of (Re(CO)3Br(THF))2 and the ligand (C6H5)2(C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.3 20112011-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000300023en10.4067/S0717-97072011000300023
institution Scielo Chile
collection Scielo Chile
language English
description We have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br] by direct reaction of (Re(CO)3Br(THF))2 and the ligand (C6H5)2(C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001.
author VENEGAS,FELIPE
PIZARRO,NANCY
VEGA,ANDRES
spellingShingle VENEGAS,FELIPE
PIZARRO,NANCY
VEGA,ANDRES
STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
author_facet VENEGAS,FELIPE
PIZARRO,NANCY
VEGA,ANDRES
author_sort VENEGAS,FELIPE
title STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
title_short STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
title_full STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
title_fullStr STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
title_full_unstemmed STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
title_sort structural and photophysical properties of a mononuclear re(i) complex:[p,n-{(c6h5)2(c5h5n)p}re(co)3br]
publisher Sociedad Chilena de Química
publishDate 2011
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000300023
work_keys_str_mv AT venegasfelipe structuralandphotophysicalpropertiesofamononuclearreicomplexpnc6h52c5h5npreco3br
AT pizarronancy structuralandphotophysicalpropertiesofamononuclearreicomplexpnc6h52c5h5npreco3br
AT vegaandres structuralandphotophysicalpropertiesofamononuclearreicomplexpnc6h52c5h5npreco3br
_version_ 1718445452990349312

Ejemplares similares