HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS

Methylenediphosphonic Acid (MDP) was found to be a simple, cheap and reusable heterogeneous catalyst for the acetylation of structurally diverse alcohols, phenols and amines with acetic anhydride under solvent-free conditions at room temperature. This method showed preferential selectivity for the a...

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Autores principales:	XIE,MINHAO, WANG,HONGYONG, WU,JUN, HE,YONGJUN, LIU,YALING, ZOU,PEI
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2011
Materias:	Bisphosphonic acid MDP Solvent-free Acetylation
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000400013
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spelling	oai:scielo:S0717-970720110004000132012-03-06HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONSXIE,MINHAOWANG,HONGYONGWU,JUNHE,YONGJUNLIU,YALINGZOU,PEI Bisphosphonic acid MDP Solvent-free Acetylation Methylenediphosphonic Acid (MDP) was found to be a simple, cheap and reusable heterogeneous catalyst for the acetylation of structurally diverse alcohols, phenols and amines with acetic anhydride under solvent-free conditions at room temperature. This method showed preferential selectivity for the acetylation of the amino group in the presence of hydroxyl group. The method is very mild and the yields were in excellent.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.4 20112011-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000400013en10.4067/S0717-97072011000400013
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Bisphosphonic acid MDP Solvent-free Acetylation
spellingShingle	Bisphosphonic acid MDP Solvent-free Acetylation XIE,MINHAO WANG,HONGYONG WU,JUN HE,YONGJUN LIU,YALING ZOU,PEI HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
description	Methylenediphosphonic Acid (MDP) was found to be a simple, cheap and reusable heterogeneous catalyst for the acetylation of structurally diverse alcohols, phenols and amines with acetic anhydride under solvent-free conditions at room temperature. This method showed preferential selectivity for the acetylation of the amino group in the presence of hydroxyl group. The method is very mild and the yields were in excellent.
author	XIE,MINHAO WANG,HONGYONG WU,JUN HE,YONGJUN LIU,YALING ZOU,PEI
author_facet	XIE,MINHAO WANG,HONGYONG WU,JUN HE,YONGJUN LIU,YALING ZOU,PEI
author_sort	XIE,MINHAO
title	HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
title_short	HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
title_full	HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
title_fullStr	HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
title_full_unstemmed	HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
title_sort	highly efficient and versatile acetylation of alcohols, phenols and amines catalyzed by methylenediphosphonic acid (mdp) under solvent-free conditions
publisher	Sociedad Chilena de Química
publishDate	2011
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000400013
work_keys_str_mv	AT xieminhao highlyefficientandversatileacetylationofalcoholsphenolsandaminescatalyzedbymethylenediphosphonicacidmdpundersolventfreeconditions AT wanghongyong highlyefficientandversatileacetylationofalcoholsphenolsandaminescatalyzedbymethylenediphosphonicacidmdpundersolventfreeconditions AT wujun highlyefficientandversatileacetylationofalcoholsphenolsandaminescatalyzedbymethylenediphosphonicacidmdpundersolventfreeconditions AT heyongjun highlyefficientandversatileacetylationofalcoholsphenolsandaminescatalyzedbymethylenediphosphonicacidmdpundersolventfreeconditions AT liuyaling highlyefficientandversatileacetylationofalcoholsphenolsandaminescatalyzedbymethylenediphosphonicacidmdpundersolventfreeconditions AT zoupei highlyefficientandversatileacetylationofalcoholsphenolsandaminescatalyzedbymethylenediphosphonicacidmdpundersolventfreeconditions
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HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS

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