SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION

A series of zinc (II) complexes has been prepared based on a β-diketiminate ligand framework and exhibits the highest rate of polymerization with better stereoselectivity in the formation of polylactic from the rac-lactide with aggregation and narrow polydisperties. Degree of aggregation an...

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Autores principales:	ATHAR,TAIMUR, HAKEEM,ABDUL, TOPNANI,NEHA
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2011
Materias:	β-diketiminato Zinc alkoxides PLA and PCL Ring opening polymerization
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000400014
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spelling	oai:scielo:S0717-970720110004000142012-03-06SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATIONATHAR,TAIMURHAKEEM,ABDULTOPNANI,NEHA β-diketiminato Zinc alkoxides PLA and PCL Ring opening polymerization A series of zinc (II) complexes has been prepared based on a β-diketiminate ligand framework and exhibits the highest rate of polymerization with better stereoselectivity in the formation of polylactic from the rac-lactide with aggregation and narrow polydisperties. Degree of aggregation and their reactivity's depends on the nature of alkoxy groups, the role of metal ion, solvent and their structural properties. The nature of substituent group on β-diketiminate ligand exerts a significant change affecting both the degree of selectivity and the rate of polymerization. The polymerizations are living, as evidenced by the narrow polydisperties and with their linear nature and average molecular weight.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.56 n.4 20112011-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000400014en10.4067/S0717-97072011000400014
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	β-diketiminato Zinc alkoxides PLA and PCL Ring opening polymerization
spellingShingle	β-diketiminato Zinc alkoxides PLA and PCL Ring opening polymerization ATHAR,TAIMUR HAKEEM,ABDUL TOPNANI,NEHA SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION
description	A series of zinc (II) complexes has been prepared based on a β-diketiminate ligand framework and exhibits the highest rate of polymerization with better stereoselectivity in the formation of polylactic from the rac-lactide with aggregation and narrow polydisperties. Degree of aggregation and their reactivity's depends on the nature of alkoxy groups, the role of metal ion, solvent and their structural properties. The nature of substituent group on β-diketiminate ligand exerts a significant change affecting both the degree of selectivity and the rate of polymerization. The polymerizations are living, as evidenced by the narrow polydisperties and with their linear nature and average molecular weight.
author	ATHAR,TAIMUR HAKEEM,ABDUL TOPNANI,NEHA
author_facet	ATHAR,TAIMUR HAKEEM,ABDUL TOPNANI,NEHA
author_sort	ATHAR,TAIMUR
title	SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION
title_short	SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION
title_full	SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION
title_fullStr	SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION
title_full_unstemmed	SYNTHESIS OF β-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION
title_sort	synthesis of β-diketiminate derivatives of zinc alkoxides: catalytic properties for ring opening polymerization
publisher	Sociedad Chilena de Química
publishDate	2011
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072011000400014
work_keys_str_mv	AT athartaimur synthesisof946diketiminatederivativesofzincalkoxidescatalyticpropertiesforringopeningpolymerization AT hakeemabdul synthesisof946diketiminatederivativesofzincalkoxidescatalyticpropertiesforringopeningpolymerization AT topnanineha synthesisof946diketiminatederivativesofzincalkoxidescatalyticpropertiesforringopeningpolymerization
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SYNTHESIS OF &#946;-DIKETIMINATE DERIVATIVES OF ZINC ALKOXIDES: CATALYTIC PROPERTIES FOR RING OPENING POLYMERIZATION

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