STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]

Complexation reactions of sarcosine with mercury(II), nickel(II) and lead(II) have been studied in the solution phase using a paper ionophoretic technique. This method is based on movement of a spot of metal ion in an electric field at various pHs of background electrolyte. A graph of pH versus mobi...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autor principal:	TEWARI,B. B
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2012
Materias:	Paper electrophoretic technique mercury(II) complexes nickel(II) complexes lead(II) complexes sarcosine stability constant
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000100009
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072012000100009
record_format	dspace
spelling	oai:scielo:S0717-970720120001000092012-07-19STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]TEWARI,B. B Paper electrophoretic technique mercury(II) complexes nickel(II) complexes lead(II) complexes sarcosine stability constant Complexation reactions of sarcosine with mercury(II), nickel(II) and lead(II) have been studied in the solution phase using a paper ionophoretic technique. This method is based on movement of a spot of metal ion in an electric field at various pHs of background electrolyte. A graph of pH versus mobility was used to obtain information on the metal complexes and to calculate stability constants. The stability constants of the ML+ and ML2 complexes of mercury(II), nickel(II) and lead(II) - sarcosine have been found to be (7.95 ± 0.02; 6.79 ± 0.06), (6.69 ± 0.01; 5.29 ± 0.04) and (4.34 ± 0.02; 2.69 ± 0.07) (logarithm stability constant values), respectively at a temperature of 35 ° C and ionic strength of 0.1 M.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.1 20122012-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000100009en10.4067/S0717-97072012000100009
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Paper electrophoretic technique mercury(II) complexes nickel(II) complexes lead(II) complexes sarcosine stability constant
spellingShingle	Paper electrophoretic technique mercury(II) complexes nickel(II) complexes lead(II) complexes sarcosine stability constant TEWARI,B. B STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]
description	Complexation reactions of sarcosine with mercury(II), nickel(II) and lead(II) have been studied in the solution phase using a paper ionophoretic technique. This method is based on movement of a spot of metal ion in an electric field at various pHs of background electrolyte. A graph of pH versus mobility was used to obtain information on the metal complexes and to calculate stability constants. The stability constants of the ML+ and ML2 complexes of mercury(II), nickel(II) and lead(II) - sarcosine have been found to be (7.95 ± 0.02; 6.79 ± 0.06), (6.69 ± 0.01; 5.29 ± 0.04) and (4.34 ± 0.02; 2.69 ± 0.07) (logarithm stability constant values), respectively at a temperature of 35 ° C and ionic strength of 0.1 M.
author	TEWARI,B. B
author_facet	TEWARI,B. B
author_sort	TEWARI,B. B
title	STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]
title_short	STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]
title_full	STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]
title_fullStr	STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]
title_full_unstemmed	STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]
title_sort	studies on complexation in solution with a paper electrophoretic technique [the system mercury(ii)/nickel(ii)/ lead(ii) - sarcosine]
publisher	Sociedad Chilena de Química
publishDate	2012
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000100009
work_keys_str_mv	AT tewaribb studiesoncomplexationinsolutionwithapaperelectrophoretictechniquethesystemmercuryiinickeliileadiisarcosine
_version_	1718445459854327808

STUDIES ON COMPLEXATION IN SOLUTION WITH A PAPER ELECTROPHORETIC TECHNIQUE [THE SYSTEM MERCURY(II)/NICKEL(II)/ LEAD(II) - SARCOSINE]

Ejemplares similares