ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE

The copolymerization of carbazole(C) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(PTO) was successfully achieved electrochemically in CH2Cl2 containing 25% boron trifluoride diethyl etherate BFEE(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures o...

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Autores principales:	GAO,CHUANG, PEI,MEISHAN, PAN,QIWEI
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2012
Materias:	Polythiophene Electrochemical polymerization carbazole Copolymerization Boron trifluoride diethyl etherate
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200019
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spelling	oai:scielo:S0717-970720120002000192014-03-10ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLEGAO,CHUANGPEI,MEISHANPAN,QIWEI Polythiophene Electrochemical polymerization carbazole Copolymerization Boron trifluoride diethyl etherate The copolymerization of carbazole(C) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(PTO) was successfully achieved electrochemically in CH2Cl2 containing 25% boron trifluoride diethyl etherate BFEE(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum or an optically transparent ITO electrode. As-formed copolymer own the advantages of PTO, such as good electrochemical behaviors, excellent ambient stability. The structure of the copolymer were investigated by UV-vis, fluorescence spectra and thermal analysis, respectively. The fluorescence spectra indicate that PPTOC films are yellow-light emitters. Thermal analysis studies confirmed PPTOC has a good thermal stability.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.2 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200019en10.4067/S0717-97072012000200019
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Polythiophene Electrochemical polymerization carbazole Copolymerization Boron trifluoride diethyl etherate
spellingShingle	Polythiophene Electrochemical polymerization carbazole Copolymerization Boron trifluoride diethyl etherate GAO,CHUANG PEI,MEISHAN PAN,QIWEI ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
description	The copolymerization of carbazole(C) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(PTO) was successfully achieved electrochemically in CH2Cl2 containing 25% boron trifluoride diethyl etherate BFEE(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum or an optically transparent ITO electrode. As-formed copolymer own the advantages of PTO, such as good electrochemical behaviors, excellent ambient stability. The structure of the copolymer were investigated by UV-vis, fluorescence spectra and thermal analysis, respectively. The fluorescence spectra indicate that PPTOC films are yellow-light emitters. Thermal analysis studies confirmed PPTOC has a good thermal stability.
author	GAO,CHUANG PEI,MEISHAN PAN,QIWEI
author_facet	GAO,CHUANG PEI,MEISHAN PAN,QIWEI
author_sort	GAO,CHUANG
title	ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_short	ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_full	ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_fullStr	ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_full_unstemmed	ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_sort	electrochemical copolymerization of cross-linkable polythiophene and carbazole
publisher	Sociedad Chilena de Química
publishDate	2012
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200019
work_keys_str_mv	AT gaochuang electrochemicalcopolymerizationofcrosslinkablepolythiopheneandcarbazole AT peimeishan electrochemicalcopolymerizationofcrosslinkablepolythiopheneandcarbazole AT panqiwei electrochemicalcopolymerizationofcrosslinkablepolythiopheneandcarbazole
_version_	1718445465882591232

ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE

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