SOL-GEL INCORPORATION OF ORGANOMETALLIC COMPOUNDS INTO SILICA: USEFUL PRECURSORS TO METALLIC NANOSTRUCTURED MATERIALS
Inclusion of the organometallic MLn = [HOC5H4N-Cp2TiCl][PF6] (1), HOC5H4N-W(CO)5 (2), HOC5H4N-Mo(CO)5 (3), [HOC6H4CH2CN-Cp2TiCl][PF6] (4), HOC6H4CH2CN-W(CO)5 (5) and HOC6H4CH2CN-Mo(CO)5 (6) into amorphous silica using the gelator precursor TEOS and N3P3{NH[CH2]3Si[OEt]3}6 afford the gels (MLn)(SiO2)...
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| Main Authors: | , , , |
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| Language: | English |
| Published: |
Sociedad Chilena de Química
2012
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| Subjects: | |
| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200021 |
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