NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN

Nanostructured poly(amide-imide) (PAI) materials have been produced by polymerizing a diamine monomer, 3,5-diamino-N-(3,4-dihydroxyphenethyl) benzamide, with four trimellitic anhydride-derived, imide ring-preformed chiral amino acid-based dicarboxylic acids. Polycondensation reactions were carried o...

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Autores principales: MALLAKPOUR,S, ZADEHNAZARI,A
Lenguaje:English
Publicado: Sociedad Chilena de Química 2012
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300011
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spelling oai:scielo:S0717-970720120003000112019-02-19NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAINMALLAKPOUR,SZADEHNAZARI,A Nanostructure green chemistry chiral polymers polycondensation Nanostructured poly(amide-imide) (PAI) materials have been produced by polymerizing a diamine monomer, 3,5-diamino-N-(3,4-dihydroxyphenethyl) benzamide, with four trimellitic anhydride-derived, imide ring-preformed chiral amino acid-based dicarboxylic acids. Polycondensation reactions were carried out in the presence of small amount of molten tetrabutylammonium bromide as a green molten salt medium and triphenyl phosphite as the activator by classical heating method. Field emission scanning electron microscopy micrographs showed that the prepared polymers are assembled by spherical particles, which are distributed uniformly and randomly, having nano-sized diameter ranged between 46-54 nm. According to X-ray diffraction patterns, all of PAIs are amorphous. They show excellent solubility in a variety of amide polar solvents and even in less polar solvents such as m-cresol and pyridine. The obtained PAIs were also characterized by Fourier transform infrared spectroscopy, ¹H NMR, elemental, and thermogravimetric analysis techniques. The effect of ultrasound on the morphology of polymers was also investigated. This study confirmed that the size of polymer particles was decreased and the shape of them was also changed.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.3 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300011en10.4067/S0717-97072012000300011
institution Scielo Chile
collection Scielo Chile
language English
topic Nanostructure
green chemistry
chiral polymers
polycondensation
spellingShingle Nanostructure
green chemistry
chiral polymers
polycondensation
MALLAKPOUR,S
ZADEHNAZARI,A
NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN
description Nanostructured poly(amide-imide) (PAI) materials have been produced by polymerizing a diamine monomer, 3,5-diamino-N-(3,4-dihydroxyphenethyl) benzamide, with four trimellitic anhydride-derived, imide ring-preformed chiral amino acid-based dicarboxylic acids. Polycondensation reactions were carried out in the presence of small amount of molten tetrabutylammonium bromide as a green molten salt medium and triphenyl phosphite as the activator by classical heating method. Field emission scanning electron microscopy micrographs showed that the prepared polymers are assembled by spherical particles, which are distributed uniformly and randomly, having nano-sized diameter ranged between 46-54 nm. According to X-ray diffraction patterns, all of PAIs are amorphous. They show excellent solubility in a variety of amide polar solvents and even in less polar solvents such as m-cresol and pyridine. The obtained PAIs were also characterized by Fourier transform infrared spectroscopy, ¹H NMR, elemental, and thermogravimetric analysis techniques. The effect of ultrasound on the morphology of polymers was also investigated. This study confirmed that the size of polymer particles was decreased and the shape of them was also changed.
author MALLAKPOUR,S
ZADEHNAZARI,A
author_facet MALLAKPOUR,S
ZADEHNAZARI,A
author_sort MALLAKPOUR,S
title NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN
title_short NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN
title_full NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN
title_fullStr NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN
title_full_unstemmed NANOSTRUCTURE FORMATION IN CHIRAL POLY(AMIDE-IMIDE)S BASED ON DOPAMINE MOIETY AND N-TRIMELLITYLIMIDO-L-AMINO ACIDS IN THE MAIN CHAIN
title_sort nanostructure formation in chiral poly(amide-imide)s based on dopamine moiety and n-trimellitylimido-l-amino acids in the main chain
publisher Sociedad Chilena de Química
publishDate 2012
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300011
work_keys_str_mv AT mallakpours nanostructureformationinchiralpolyamideimidesbasedondopaminemoietyandntrimellitylimidolaminoacidsinthemainchain
AT zadehnazaria nanostructureformationinchiralpolyamideimidesbasedondopaminemoietyandntrimellitylimidolaminoacidsinthemainchain
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