PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE

A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure anal...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: ALHADI,ABEER A, SHAKER,SHAYMA A, SULEIMAN G,NURA, YEHYE,WAGEE A, MOHD ALI,HAPIPAH
Lenguaje:English
Publicado: Sociedad Chilena de Química 2012
Materias:
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300018
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:scielo:S0717-97072012000300018
record_format dspace
spelling oai:scielo:S0717-970720120003000182019-02-19PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONEALHADI,ABEER ASHAKER,SHAYMA ASULEIMAN G,NURAYEHYE,WAGEE AMOHD ALI,HAPIPAH Schiff base derivatives Cd(II) complexes hydrazone derivatives complexes spectroscopic characterization A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, ¹H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.3 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300018en10.4067/S0717-97072012000300018
institution Scielo Chile
collection Scielo Chile
language English
topic Schiff base derivatives
Cd(II) complexes
hydrazone derivatives complexes
spectroscopic characterization
spellingShingle Schiff base derivatives
Cd(II) complexes
hydrazone derivatives complexes
spectroscopic characterization
ALHADI,ABEER A
SHAKER,SHAYMA A
SULEIMAN G,NURA
YEHYE,WAGEE A
MOHD ALI,HAPIPAH
PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
description A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, ¹H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms.
author ALHADI,ABEER A
SHAKER,SHAYMA A
SULEIMAN G,NURA
YEHYE,WAGEE A
MOHD ALI,HAPIPAH
author_facet ALHADI,ABEER A
SHAKER,SHAYMA A
SULEIMAN G,NURA
YEHYE,WAGEE A
MOHD ALI,HAPIPAH
author_sort ALHADI,ABEER A
title PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_short PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_full PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_fullStr PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_full_unstemmed PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_sort preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone
publisher Sociedad Chilena de Química
publishDate 2012
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300018
work_keys_str_mv AT alhadiabeera preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT shakershaymaa preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT suleimangnura preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT yehyewageea preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT mohdalihapipah preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
_version_ 1718445470852841472