SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES

A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and t...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	GUARDA,L, PARRA,N, CHAVEZ,M. S, BELMAR,J, JIMENEZ,C. A, PASAN,J, RUIZ-PEREZ,C
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2012
Materias:	Acylating Agents Ligands design Amides
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300023
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072012000300023
record_format	dspace
spelling	oai:scielo:S0717-970720120003000232019-02-19SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINESGUARDA,LPARRA,NCHAVEZ,M. SBELMAR,JJIMENEZ,C. APASAN,JRUIZ-PEREZ,C Acylating Agents Ligands design Amides A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and tris-amides 4a-4e. The yields ranged from good to very good and showed that choosing the right acylating agent is a key point in this synthesis. All the compounds were characterized by elemental analysis, FTIR, and ¹H NMR.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.3 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300023en10.4067/S0717-97072012000300023
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Acylating Agents Ligands design Amides
spellingShingle	Acylating Agents Ligands design Amides GUARDA,L PARRA,N CHAVEZ,M. S BELMAR,J JIMENEZ,C. A PASAN,J RUIZ-PEREZ,C SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES
description	A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and tris-amides 4a-4e. The yields ranged from good to very good and showed that choosing the right acylating agent is a key point in this synthesis. All the compounds were characterized by elemental analysis, FTIR, and ¹H NMR.
author	GUARDA,L PARRA,N CHAVEZ,M. S BELMAR,J JIMENEZ,C. A PASAN,J RUIZ-PEREZ,C
author_facet	GUARDA,L PARRA,N CHAVEZ,M. S BELMAR,J JIMENEZ,C. A PASAN,J RUIZ-PEREZ,C
author_sort	GUARDA,L
title	SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES
title_short	SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES
title_full	SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES
title_fullStr	SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES
title_full_unstemmed	SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES
title_sort	synthesis and characterization of bis- and tos-(4-carboxybenzoyl)-alkaneamines
publisher	Sociedad Chilena de Química
publishDate	2012
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300023
work_keys_str_mv	AT guardal synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines AT parran synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines AT chavezms synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines AT belmarj synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines AT jimenezca synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines AT pasanj synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines AT ruizperezc synthesisandcharacterizationofbisandtos4carboxybenzoylalkaneamines
_version_	1718445471707430912

SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES

Ejemplares similares