EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I

The effect of some natural UV absorbers on the photostabilization of spiroketal enol ethers (en-yn-dicycloethers) present in German Chamomille extracts pre-coated on glass plates (solid phase) was examined. Plates were exposed to sunlight radiation from a UV-sun radiation lamp, in the presence and a...

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Autores principales: LUCERO,A, REBOLLEDO,C, BUONO-CORE,G.E
Lenguaje:English
Publicado: Sociedad Chilena de Química 2012
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300024
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spelling oai:scielo:S0717-970720120003000242019-02-19EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART ILUCERO,AREBOLLEDO,CBUONO-CORE,G.E spiroketal enol ethers German Chamomille photostabilization UV absorbers The effect of some natural UV absorbers on the photostabilization of spiroketal enol ethers (en-yn-dicycloethers) present in German Chamomille extracts pre-coated on glass plates (solid phase) was examined. Plates were exposed to sunlight radiation from a UV-sun radiation lamp, in the presence and absence of gallic acid, cinnamic acid, caffeic acid, ferulic acid and aloin, all natural UV absorbers. At particular intervals the remaining concentration of the en-yn-dicycloethers was analyzed by HPLC. Using first-order kinetic equation, the dissipation half-life values (DT50) for the degradation of the en-yn-dicycloethers under UV-sun radiation were obtained. The results showed that the addition of cumaric acid and caffeic acid provided moderate degree of photostabilization of the en-yn-dicycloethers and that addition of ferulic acid provided the best photostabilization among the UV absorbers studied. Photostabilization effect appears to be due to a competitive energy absorption of UV photons by the absorber molecules.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.3 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300024en10.4067/S0717-97072012000300024
institution Scielo Chile
collection Scielo Chile
language English
topic spiroketal enol ethers
German Chamomille
photostabilization
UV absorbers
spellingShingle spiroketal enol ethers
German Chamomille
photostabilization
UV absorbers
LUCERO,A
REBOLLEDO,C
BUONO-CORE,G.E
EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I
description The effect of some natural UV absorbers on the photostabilization of spiroketal enol ethers (en-yn-dicycloethers) present in German Chamomille extracts pre-coated on glass plates (solid phase) was examined. Plates were exposed to sunlight radiation from a UV-sun radiation lamp, in the presence and absence of gallic acid, cinnamic acid, caffeic acid, ferulic acid and aloin, all natural UV absorbers. At particular intervals the remaining concentration of the en-yn-dicycloethers was analyzed by HPLC. Using first-order kinetic equation, the dissipation half-life values (DT50) for the degradation of the en-yn-dicycloethers under UV-sun radiation were obtained. The results showed that the addition of cumaric acid and caffeic acid provided moderate degree of photostabilization of the en-yn-dicycloethers and that addition of ferulic acid provided the best photostabilization among the UV absorbers studied. Photostabilization effect appears to be due to a competitive energy absorption of UV photons by the absorber molecules.
author LUCERO,A
REBOLLEDO,C
BUONO-CORE,G.E
author_facet LUCERO,A
REBOLLEDO,C
BUONO-CORE,G.E
author_sort LUCERO,A
title EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I
title_short EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I
title_full EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I
title_fullStr EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I
title_full_unstemmed EFFECT OF SOME NATURAL UV-ABSORBERS ON THE PHOTOSTABILIZATION OF ACTIVE INGREDIENTS IN GERMAN CHAMOMILLE FLORAL EXTRACTS: PART I
title_sort effect of some natural uv-absorbers on the photostabilization of active ingredients in german chamomille floral extracts: part i
publisher Sociedad Chilena de Química
publishDate 2012
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300024
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AT rebolledoc effectofsomenaturaluvabsorbersonthephotostabilizationofactiveingredientsingermanchamomillefloralextractsparti
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