A FACILE SYNTHESIS OF POROUS HEMATITE NANOMATERIALS AND THEIR FAST SORPTION OF CR (VI) IN WASTEWATER

Porous hematite (a-Fe2O3) nanomaterials can be simply acquired from amorphous iron (III) hydroxide (Fe (OH) 3) in neutral solution by an evaporation method in an open quartz flask in a vacuum drying oven. Results show that the as-obtained a-Fe2O3 particles at 180°C for 2h or so are nearly spindle in...

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Autores principales: HAN,CHENGLIANG, XIE,JINGSONG, DENG,CHONGHAI, ZHAO,DIFANG
Lenguaje:English
Publicado: Sociedad Chilena de Química 2012
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000400008
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Sumario:Porous hematite (a-Fe2O3) nanomaterials can be simply acquired from amorphous iron (III) hydroxide (Fe (OH) 3) in neutral solution by an evaporation method in an open quartz flask in a vacuum drying oven. Results show that the as-obtained a-Fe2O3 particles at 180°C for 2h or so are nearly spindle in shape. Each of a-Fe2O3 microspindles is made of many ultrafine a-Fe2O3 nanoparticles and results in a porous structure. The as-prepared porous a-Fe2O3 powders have higher surface area (~78m²/g) and can rapidly remove Cr (VI) ions in wastewater at room temperature. The model of the adsorption kinetic of Cr (VI) is best adapted to the pseudo second-order equation.