CEFOPERAZONE METAL COMPLEXES: SYNTHESIS AND CHARACTERIZATION

Cefoperazone (Hcefopz) interacts with transition metal(II) ions to give [M(cefopz)Cl] complexes (M = Fe, Co, Ni, Cu and Cd) and [Fe(cefopz)Cl]Cl which were characterized by physicochemical and spectroscopic methods. The spectra indicated that the antibiotics act as monoanionic multidentate NO3 chela...

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Autores principales: ANACONA,J.R, BRAVO,ALINA, LOPEZ,MARIA E
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000100004
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Sumario:Cefoperazone (Hcefopz) interacts with transition metal(II) ions to give [M(cefopz)Cl] complexes (M = Fe, Co, Ni, Cu and Cd) and [Fe(cefopz)Cl]Cl which were characterized by physicochemical and spectroscopic methods. The spectra indicated that the antibiotics act as monoanionic multidentate NO3 chelating agent towards metal ions, via the amides, and carboxylate and N-azomoiety. The complexes are non-toxic, insoluble in water and common organic solvents and probably have polymeric structures.