PALLADIUM COMPLEX BEARING 3,5-BIS(BENZOTRIAZOL-1-YLMETHYL)TOLUENE LIGAND CATALYZES OXIDATIVE AMINATION OF ALLYL BUTYL ETHER
The reaction of 3,5-bis(bromomethyl)toluene with benzotriazole yields the bidentate ligand 3,5-bis(benzotriazol-1-ylmethyl)toluene (1). This ligand reacts with [PdCl2(cod)] (cod = 1,5-cyclooctadiene) to give the complex [PdCl2{3,5-bis(benzotriazol-1-ylmethyl)tolyl}] (2). These compounds were charact...
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Autores principales: | , , , |
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Lenguaje: | English |
Publicado: |
Sociedad Chilena de Química
2013
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Materias: | |
Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000100007 |
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Sumario: | The reaction of 3,5-bis(bromomethyl)toluene with benzotriazole yields the bidentate ligand 3,5-bis(benzotriazol-1-ylmethyl)toluene (1). This ligand reacts with [PdCl2(cod)] (cod = 1,5-cyclooctadiene) to give the complex [PdCl2{3,5-bis(benzotriazol-1-ylmethyl)tolyl}] (2). These compounds were characterized by elemental analyses, mass spectra, and FTIR and NMR (¹H, 13C) spectroscopies. The palladium(II) complex 2 shows high activity as catalyst for oxidative amination, involving allyl butyl ether and phthalimide as substrates and PhICl2 as a stoichiometric oxidant. |
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