THEORETICAL STUDY OF COMPLEXES OF THE TYPE [Pt3(M-L)3(L')3J-X (L=CO,SO2,CNH; L'=PH3,CNH; X=Tl+, Hg0, MPH3+ (M = Cu, Au, Ag))

THEORETICAL STUDY OF COMPLEXES OF THE TYPE [Pt3(M-L)3(L')3J-X (L=CO,SO2,CNH; L'=PH3,CNH; X=Tl+, Hg0, MPH3+ (M = Cu, Au, Ag))

The interaction between the [(μ-L)3(L')3] cluster (L = CO, SO2, CNH; L = PH3, CNH) and a series of fragments X (Tl+, Hg(0), AuPH3+, CuPH3+ and AgPH3+) was studied using ab initio methodology. The calculations suggest that the complexes formed are stable. We have studied these complexes...

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Autores principales: MENDIZABAL,FERNANDO, DONOSO,DANIELA, SALATAR,RICHARD
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
Materias:
Platinum clusters
metallic interactions
reactivity
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000100014
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