TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES

Reaction of [MoO2(acac)2] (where acac = acetylacetonate) with two similar hydrazone ligands in methanol yielded two water coordinated mononuclear molybdenum(VI) oxo complexes with general formula [MoO2L(OH2)], where L = L¹ = N'-(2-hydroxy-3-methoxybenzylidene)-2-methoxybenzohydrazide (H2L¹), an...

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Autores principales:	QIAN,SHAO-SONG, ZHEN,MIAO-MIAO, ZHAO,YUE, ZHANG,NA, YOU,ZHONG-LU, ZHU,HAI-LIANG
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Materias:	molybdenum complex hydrazone ligand crystal structure X-ray diffraction
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000100031
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spelling	oai:scielo:S0717-970720130001000312014-09-09TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURESQIAN,SHAO-SONGZHEN,MIAO-MIAOZHAO,YUEZHANG,NAYOU,ZHONG-LUZHU,HAI-LIANG molybdenum complex hydrazone ligand crystal structure X-ray diffraction Reaction of [MoO2(acac)2] (where acac = acetylacetonate) with two similar hydrazone ligands in methanol yielded two water coordinated mononuclear molybdenum(VI) oxo complexes with general formula [MoO2L(OH2)], where L = L¹ = N'-(2-hydroxy-3-methoxybenzylidene)-2-methoxybenzohydrazide (H2L¹), and L = L² = N'-(3-ethoxy-2-hydroxybenzylidene)-2-methoxybenzohydrazide (H2L²). Crystal and molecular structures of the complexes were determined by single crystal X-ray diffraction method. All of the investigated compounds were further characterized by elemental analysis and FT-IR spectra. Single crystal X-ray structural studies indicate that the hydrazone ligands coordinate to the MoO2 cores through enolate oxygen, phenolate oxygen and azomethine nitrogen. The Mo atoms in both complexes are in octahedral coordination.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.1 20132013-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000100031en10.4067/S0717-97072013000100031
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	molybdenum complex hydrazone ligand crystal structure X-ray diffraction
spellingShingle	molybdenum complex hydrazone ligand crystal structure X-ray diffraction QIAN,SHAO-SONG ZHEN,MIAO-MIAO ZHAO,YUE ZHANG,NA YOU,ZHONG-LU ZHU,HAI-LIANG TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES
description	Reaction of [MoO2(acac)2] (where acac = acetylacetonate) with two similar hydrazone ligands in methanol yielded two water coordinated mononuclear molybdenum(VI) oxo complexes with general formula [MoO2L(OH2)], where L = L¹ = N'-(2-hydroxy-3-methoxybenzylidene)-2-methoxybenzohydrazide (H2L¹), and L = L² = N'-(3-ethoxy-2-hydroxybenzylidene)-2-methoxybenzohydrazide (H2L²). Crystal and molecular structures of the complexes were determined by single crystal X-ray diffraction method. All of the investigated compounds were further characterized by elemental analysis and FT-IR spectra. Single crystal X-ray structural studies indicate that the hydrazone ligands coordinate to the MoO2 cores through enolate oxygen, phenolate oxygen and azomethine nitrogen. The Mo atoms in both complexes are in octahedral coordination.
author	QIAN,SHAO-SONG ZHEN,MIAO-MIAO ZHAO,YUE ZHANG,NA YOU,ZHONG-LU ZHU,HAI-LIANG
author_facet	QIAN,SHAO-SONG ZHEN,MIAO-MIAO ZHAO,YUE ZHANG,NA YOU,ZHONG-LU ZHU,HAI-LIANG
author_sort	QIAN,SHAO-SONG
title	TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES
title_short	TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES
title_full	TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES
title_fullStr	TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES
title_full_unstemmed	TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES
title_sort	two water-coordinated mononuclear molybdenum(vi) oxo complexes with similar tridentate hydrazone ligands: synthesis and crystal structures
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000100031
work_keys_str_mv	AT qianshaosong twowatercoordinatedmononuclearmolybdenumvioxocomplexeswithsimilartridentatehydrazoneligandssynthesisandcrystalstructures AT zhenmiaomiao twowatercoordinatedmononuclearmolybdenumvioxocomplexeswithsimilartridentatehydrazoneligandssynthesisandcrystalstructures AT zhaoyue twowatercoordinatedmononuclearmolybdenumvioxocomplexeswithsimilartridentatehydrazoneligandssynthesisandcrystalstructures AT zhangna twowatercoordinatedmononuclearmolybdenumvioxocomplexeswithsimilartridentatehydrazoneligandssynthesisandcrystalstructures AT youzhonglu twowatercoordinatedmononuclearmolybdenumvioxocomplexeswithsimilartridentatehydrazoneligandssynthesisandcrystalstructures AT zhuhailiang twowatercoordinatedmononuclearmolybdenumvioxocomplexeswithsimilartridentatehydrazoneligandssynthesisandcrystalstructures
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TWO WATER-COORDINATED MONONUCLEAR MOLYBDENUM(VI) OXO COMPLEXES WITH SIMILAR TRIDENTATE HYDRAZONE LIGANDS: SYNTHESIS AND CRYSTAL STRUCTURES

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