KINETICS AND MECHANISM OF BASE HYDROLYSIS OF A-AMINOACID ESTERS CATALYSED BY [Pd(1,3- DIAMINO-2-HYDROXYPROPANE)(H2O)2]2+ COMPLEX
Amino acid esters (L) react with [Pd(DHP(H2O)2]²+ , (DHP = 1,3-diamino-2-hydroxopropane) giving mixed ligand [Pd(DHP)L]²+ The kinetics of hydrolysis of [Pd(DHP)L]²+ have been studied by pH-stat technique and rate constants were obtained. Rate acceleration observed for glycine methyl ester is high. T...
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| Autores principales: | , , |
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| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2013
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| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000200013 |
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