SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING
A novel kind of porous CuS golf balls with an average diameter of 2 µm have been successfully synthesized by using CuCl powders as source PVP as soft template based on a template-directed approach. This process involves the conversion of CuCl to CuS via reaction with H2S, which is produced by hydrol...
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Sociedad Chilena de Química
2013
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oai:scielo:S0717-970720130002000172014-09-09SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSINGXU,JUNCUIZHANG,JUNJUNYAO,CHENGLIDONG,HUAZE CuS golf balls gas sensing template-directed approach A novel kind of porous CuS golf balls with an average diameter of 2 µm have been successfully synthesized by using CuCl powders as source PVP as soft template based on a template-directed approach. This process involves the conversion of CuCl to CuS via reaction with H2S, which is produced by hydrolyzing thiourea. The transformation of oxidation state of Cu+ to Cu2+ can proceed smoothly due to the larger lattice energy of CuS in comparison with that of CuCl. The as-prepared samples have been characterized by X-ray diffraction, scanning electron microscopy and photoluminescence analysis. NH3 sensing properties of CuS golf balls with arrays of dimples and indentations have been investigated at room temperature with a simply adapted photoluminescence-type gas sensor. The results reveal that the porous CuS golf balls sensor exhibited excellent performances with a short respond time about 33 s and a short recovery time 44 s respectively.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.2 20132013-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000200017en10.4067/S0717-97072013000200017 |
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Scielo Chile |
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Scielo Chile |
language |
English |
topic |
CuS golf balls gas sensing template-directed approach |
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CuS golf balls gas sensing template-directed approach XU,JUNCUI ZHANG,JUNJUN YAO,CHENGLI DONG,HUAZE SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING |
description |
A novel kind of porous CuS golf balls with an average diameter of 2 µm have been successfully synthesized by using CuCl powders as source PVP as soft template based on a template-directed approach. This process involves the conversion of CuCl to CuS via reaction with H2S, which is produced by hydrolyzing thiourea. The transformation of oxidation state of Cu+ to Cu2+ can proceed smoothly due to the larger lattice energy of CuS in comparison with that of CuCl. The as-prepared samples have been characterized by X-ray diffraction, scanning electron microscopy and photoluminescence analysis. NH3 sensing properties of CuS golf balls with arrays of dimples and indentations have been investigated at room temperature with a simply adapted photoluminescence-type gas sensor. The results reveal that the porous CuS golf balls sensor exhibited excellent performances with a short respond time about 33 s and a short recovery time 44 s respectively. |
author |
XU,JUNCUI ZHANG,JUNJUN YAO,CHENGLI DONG,HUAZE |
author_facet |
XU,JUNCUI ZHANG,JUNJUN YAO,CHENGLI DONG,HUAZE |
author_sort |
XU,JUNCUI |
title |
SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING |
title_short |
SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING |
title_full |
SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING |
title_fullStr |
SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING |
title_full_unstemmed |
SYNTHESIS OF NOVEL HIGHLY POROUS CuS GOLF BALLS BY HYDROTHERMAL METHOD AND THEIR APPLICATION IN AMMONIA GAS SENSING |
title_sort |
synthesis of novel highly porous cus golf balls by hydrothermal method and their application in ammonia gas sensing |
publisher |
Sociedad Chilena de Química |
publishDate |
2013 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000200017 |
work_keys_str_mv |
AT xujuncui synthesisofnovelhighlyporouscusgolfballsbyhydrothermalmethodandtheirapplicationinammoniagassensing AT zhangjunjun synthesisofnovelhighlyporouscusgolfballsbyhydrothermalmethodandtheirapplicationinammoniagassensing AT yaochengli synthesisofnovelhighlyporouscusgolfballsbyhydrothermalmethodandtheirapplicationinammoniagassensing AT donghuaze synthesisofnovelhighlyporouscusgolfballsbyhydrothermalmethodandtheirapplicationinammoniagassensing |
_version_ |
1718445487365816320 |