STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE

STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE

Reaction of L (L=butane-1,2-diyl bis(pyridine-3-carboxylate) with AgBF4 in a 1:1 ratio afforded crystals of [Ag(L)(BF4)]∞ which proved to be a one-dimensional linear polymeric chain. This compound crystallizes in the space group C2/c. In the crystal structure the linear chains are connecte...

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Autores principales: BRITO,IVÁN, VALLEJOS,JAVIER, CÁRDENAS,ALEJANDRO, BOLTE,MICHAEL
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300005
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spelling oai:scielo:S0717-970720130003000052014-09-09STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATEBRITO,IVÁNVALLEJOS,JAVIERCÁRDENAS,ALEJANDROBOLTE,MICHAELReaction of L (L=butane-1,2-diyl bis(pyridine-3-carboxylate) with AgBF4 in a 1:1 ratio afforded crystals of [Ag(L)(BF4)]∞ which proved to be a one-dimensional linear polymeric chain. This compound crystallizes in the space group C2/c. In the crystal structure the linear chains are connected to another one via hydrogen bonds involving C15 as the donor atom, and O1 of the carboxylate group as the acceptor atom, thereby generating R²2(20) centrosymmetric rings to form a two-dimensional supramolecular aggregate. The thermogravimetric analysis shows that this compound is thermally stable up to 298 °C. The decomposition process is produced in one stage. The weight loss occurs from 298 to 780 °C, which is attributable to the complete removal of the ligand molecule and BF4 anion.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.3 20132013-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300005en10.4067/S0717-97072013000300005
institution Scielo Chile
collection Scielo Chile
language English
description Reaction of L (L=butane-1,2-diyl bis(pyridine-3-carboxylate) with AgBF4 in a 1:1 ratio afforded crystals of [Ag(L)(BF4)]∞ which proved to be a one-dimensional linear polymeric chain. This compound crystallizes in the space group C2/c. In the crystal structure the linear chains are connected to another one via hydrogen bonds involving C15 as the donor atom, and O1 of the carboxylate group as the acceptor atom, thereby generating R²2(20) centrosymmetric rings to form a two-dimensional supramolecular aggregate. The thermogravimetric analysis shows that this compound is thermally stable up to 298 °C. The decomposition process is produced in one stage. The weight loss occurs from 298 to 780 °C, which is attributable to the complete removal of the ligand molecule and BF4 anion.
author BRITO,IVÁN
VALLEJOS,JAVIER
CÁRDENAS,ALEJANDRO
BOLTE,MICHAEL
spellingShingle BRITO,IVÁN
VALLEJOS,JAVIER
CÁRDENAS,ALEJANDRO
BOLTE,MICHAEL
STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE
author_facet BRITO,IVÁN
VALLEJOS,JAVIER
CÁRDENAS,ALEJANDRO
BOLTE,MICHAEL
author_sort BRITO,IVÁN
title STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE
title_short STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE
title_full STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE
title_fullStr STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE
title_full_unstemmed STRUCTURAL AND THERMAL STUDY OF A NEW COORDINATION POLYMER POLY-BIS (μ2-BUTANE-1,2-DIYL BIS (PYRIDINE-3-CARBOXYLATE) K²N,N-SILVER(I) TETRAFLUOROBORATE
title_sort structural and thermal study of a new coordination polymer poly-bis (μ2-butane-1,2-diyl bis (pyridine-3-carboxylate) k²n,n-silver(i) tetrafluoroborate
publisher Sociedad Chilena de Química
publishDate 2013
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300005
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AT vallejosjavier structuralandthermalstudyofanewcoordinationpolymerpolybis9562butane12diylbispyridine3carboxylatek2nnsilveritetrafluoroborate
AT cardenasalejandro structuralandthermalstudyofanewcoordinationpolymerpolybis9562butane12diylbispyridine3carboxylatek2nnsilveritetrafluoroborate
AT boltemichael structuralandthermalstudyofanewcoordinationpolymerpolybis9562butane12diylbispyridine3carboxylatek2nnsilveritetrafluoroborate
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