TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES

Schiff base ligands 2-bromo-4-chloro-6-[(2-piperidin-1-ylethylimino)methyl]phenol (BCP) and 2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl]phenol (DBP) and their nickel(II) and copper(II) complexes [Ni(BCP)2(CH3OH)2]2NO3 (1) and [Cu(DBP)2] (2), have been prepared and characterized by elemental an...

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Autores principales:	LI,QING-BIN, XUE,LING-WEI, YANG,WEI-CHUN, ZHAO,GAN-QING
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Materias:	Schiff base nickel complex copper complex crystal structure
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300019
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spelling	oai:scielo:S0717-970720130003000192014-09-09TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURESLI,QING-BINXUE,LING-WEIYANG,WEI-CHUNZHAO,GAN-QING Schiff base nickel complex copper complex crystal structure Schiff base ligands 2-bromo-4-chloro-6-[(2-piperidin-1-ylethylimino)methyl]phenol (BCP) and 2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl]phenol (DBP) and their nickel(II) and copper(II) complexes [Ni(BCP)2(CH3OH)2]2NO3 (1) and [Cu(DBP)2] (2), have been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination. The crystal of (1) is orthorhombic: space group Pbcn, a = 23.894(1), b = 8.244(2), c = 19.900(2) Å, V = 3919.9(10) Å3, Z = 4. The crystal of (2) is monoclinic: space group P2(1)/c, a = 7.072(2), b = 15.426(3), c = 14.214(3) Å, β = 96.718(2)°, V = 1540.0(7) Å3, Z = 2. The Schiff bases coordinate to the metal atoms through the phenolate O and imine N atoms. The Ni atom in (1) is in an octahedral coordination, and the Cu atom in (2) is in a square planar coordination.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.3 20132013-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300019en10.4067/S0717-97072013000300019
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Schiff base nickel complex copper complex crystal structure
spellingShingle	Schiff base nickel complex copper complex crystal structure LI,QING-BIN XUE,LING-WEI YANG,WEI-CHUN ZHAO,GAN-QING TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES
description	Schiff base ligands 2-bromo-4-chloro-6-[(2-piperidin-1-ylethylimino)methyl]phenol (BCP) and 2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl]phenol (DBP) and their nickel(II) and copper(II) complexes [Ni(BCP)2(CH3OH)2]2NO3 (1) and [Cu(DBP)2] (2), have been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination. The crystal of (1) is orthorhombic: space group Pbcn, a = 23.894(1), b = 8.244(2), c = 19.900(2) Å, V = 3919.9(10) Å3, Z = 4. The crystal of (2) is monoclinic: space group P2(1)/c, a = 7.072(2), b = 15.426(3), c = 14.214(3) Å, β = 96.718(2)°, V = 1540.0(7) Å3, Z = 2. The Schiff bases coordinate to the metal atoms through the phenolate O and imine N atoms. The Ni atom in (1) is in an octahedral coordination, and the Cu atom in (2) is in a square planar coordination.
author	LI,QING-BIN XUE,LING-WEI YANG,WEI-CHUN ZHAO,GAN-QING
author_facet	LI,QING-BIN XUE,LING-WEI YANG,WEI-CHUN ZHAO,GAN-QING
author_sort	LI,QING-BIN
title	TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES
title_short	TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES
title_full	TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES
title_fullStr	TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES
title_full_unstemmed	TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES
title_sort	two new schiff base ni ii and cu ii complexes: synthesis and structures
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300019
work_keys_str_mv	AT liqingbin twonewschiffbaseniiiandcuiicomplexessynthesisandstructures AT xuelingwei twonewschiffbaseniiiandcuiicomplexessynthesisandstructures AT yangweichun twonewschiffbaseniiiandcuiicomplexessynthesisandstructures AT zhaoganqing twonewschiffbaseniiiandcuiicomplexessynthesisandstructures
_version_	1718445494121791488

TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES

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