A FAST PROCEDURE FOR THE PREPARATION OF BENZIMIDAZOLE DERIVATIVES USING POLYMER-SUPPORTED WITH TRIFLUOROMETHANESULFONIC ACID AS NOVEL AND REUSABLE CATALYST

A highly selective synthesis of benzimidazoles from the reaction of o-phenylenediamines and aromatic aldehydes in the presence of PVP- trifluoromethanesul-fonic acid is reported, and morphological investigation was reported by FT-IR. The remarkable advantages of this method are the simple experiment...

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Autores principales: KARAMI,CHANGIZ, GHODRATI,KEIVAN, IZADI,MINA, FARROKH,AZITA, JAFARI,SEDIGHEH, MAHMOUDIYANI,MARYAM, HAGHNAZARI,NAHID
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300026
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Sumario:A highly selective synthesis of benzimidazoles from the reaction of o-phenylenediamines and aromatic aldehydes in the presence of PVP- trifluoromethanesul-fonic acid is reported, and morphological investigation was reported by FT-IR. The remarkable advantages of this method are the simple experimental procedures, shorter reaction times, high yields of product, and non-toxic catalyst. However, the reactions were performed in solvent-free and the catalyst could be reused for several runs.