DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION

Data treatment and determination of the standard heterogeneous rate constant of simple ET process (simple electron transfer) & number of electrons consumed in electrode reaction were carried out via convolution-deconvolution voltammetry and digital simulation methods. The working curves requ...

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Autores principales:	EL-HALLAG,I.S., ASIRI,A.M., EL-MOSSALAMY,E.H.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Materias:	ET process convolutive voltammetry digital simulation electroactive species working curves
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300028
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spelling	oai:scielo:S0717-970720130003000282014-09-09DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATIONEL-HALLAG,I.S.ASIRI,A.M.EL-MOSSALAMY,E.H. ET process convolutive voltammetry digital simulation electroactive species working curves Data treatment and determination of the standard heterogeneous rate constant of simple ET process (simple electron transfer) & number of electrons consumed in electrode reaction were carried out via convolution-deconvolution voltammetry and digital simulation methods. The working curves required for determination of the standard heterogeneous rate constant, k s, were constructed and discussed. The number of electrons, n, consumed in electrode reaction was calculated via simple method. The electro-reduction of Pb2+ was carried out at hanging mercury drop electrode while the redox behaviour of Fe3+ /Fe2+ couple was performed at glassy carbon electrode to confirm the validity of the reported method in calculation of k s and n in case of simple ET.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.3 20132013-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300028en10.4067/S0717-97072013000300028
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	ET process convolutive voltammetry digital simulation electroactive species working curves
spellingShingle	ET process convolutive voltammetry digital simulation electroactive species working curves EL-HALLAG,I.S. ASIRI,A.M. EL-MOSSALAMY,E.H. DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION
description	Data treatment and determination of the standard heterogeneous rate constant of simple ET process (simple electron transfer) & number of electrons consumed in electrode reaction were carried out via convolution-deconvolution voltammetry and digital simulation methods. The working curves required for determination of the standard heterogeneous rate constant, k s, were constructed and discussed. The number of electrons, n, consumed in electrode reaction was calculated via simple method. The electro-reduction of Pb2+ was carried out at hanging mercury drop electrode while the redox behaviour of Fe3+ /Fe2+ couple was performed at glassy carbon electrode to confirm the validity of the reported method in calculation of k s and n in case of simple ET.
author	EL-HALLAG,I.S. ASIRI,A.M. EL-MOSSALAMY,E.H.
author_facet	EL-HALLAG,I.S. ASIRI,A.M. EL-MOSSALAMY,E.H.
author_sort	EL-HALLAG,I.S.
title	DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION
title_short	DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION
title_full	DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION
title_fullStr	DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION
title_full_unstemmed	DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION
title_sort	data analysis and evaluation of the electrochemical parameters for the et process via convolutive voltammetry and digital simulation
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000300028
work_keys_str_mv	AT elhallagis dataanalysisandevaluationoftheelectrochemicalparametersfortheetprocessviaconvolutivevoltammetryanddigitalsimulation AT asiriam dataanalysisandevaluationoftheelectrochemicalparametersfortheetprocessviaconvolutivevoltammetryanddigitalsimulation AT elmossalamyeh dataanalysisandevaluationoftheelectrochemicalparametersfortheetprocessviaconvolutivevoltammetryanddigitalsimulation
_version_	1718445495783784448

DATA ANALYSIS AND EVALUATION OF THE ELECTROCHEMICAL PARAMETERS FOR THE ET PROCESS VIA CONVOLUTIVE VOLTAMMETRY AND DIGITAL SIMULATION

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