SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
Spinel LiFe xCo2-xO4 samples with 0.25≤x≤1 were synthesized by the sol-gel Pechini method at 300ºC in order to study the impact on their structural and electrochemical properties due to the substitution of Co by Fe. The specific capacity for lithium insertion into the electrode m...
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Sociedad Chilena de Química
2013
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oai:scielo:S0717-970720130004000222014-09-02SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTIONMUCHNICK,NICOLEHERRERA,FRANCISCOALBURQUENQUE,DANIELAPASTENE,RUBENORTIZ,JUANGAUTIER,JUAN LUIS Lithium- Ferrites spinels diffusion coefficient Li-ion batteries sol-gel Spinel LiFe xCo2-xO4 samples with 0.25≤x≤1 were synthesized by the sol-gel Pechini method at 300ºC in order to study the impact on their structural and electrochemical properties due to the substitution of Co by Fe. The specific capacity for lithium insertion into the electrode materials depend on lithium diffusion coefficient DLi which in turn depends on the Fe³+/(Fe³++Co³+ +Co4+) octahedral cationic ratio.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400022en10.4067/S0717-97072013000400022 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Lithium- Ferrites spinels diffusion coefficient Li-ion batteries sol-gel |
spellingShingle |
Lithium- Ferrites spinels diffusion coefficient Li-ion batteries sol-gel MUCHNICK,NICOLE HERRERA,FRANCISCO ALBURQUENQUE,DANIELA PASTENE,RUBEN ORTIZ,JUAN GAUTIER,JUAN LUIS SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION |
description |
Spinel LiFe xCo2-xO4 samples with 0.25≤x≤1 were synthesized by the sol-gel Pechini method at 300ºC in order to study the impact on their structural and electrochemical properties due to the substitution of Co by Fe. The specific capacity for lithium insertion into the electrode materials depend on lithium diffusion coefficient DLi which in turn depends on the Fe³+/(Fe³++Co³+ +Co4+) octahedral cationic ratio. |
author |
MUCHNICK,NICOLE HERRERA,FRANCISCO ALBURQUENQUE,DANIELA PASTENE,RUBEN ORTIZ,JUAN GAUTIER,JUAN LUIS |
author_facet |
MUCHNICK,NICOLE HERRERA,FRANCISCO ALBURQUENQUE,DANIELA PASTENE,RUBEN ORTIZ,JUAN GAUTIER,JUAN LUIS |
author_sort |
MUCHNICK,NICOLE |
title |
SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION |
title_short |
SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION |
title_full |
SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION |
title_fullStr |
SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION |
title_full_unstemmed |
SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION |
title_sort |
spinel life xco2-xo4 (0.25 ≤ x ≤ 1) as cathodes in lithium batteries: relationship between ionic distribution and lithium ion insertion |
publisher |
Sociedad Chilena de Química |
publishDate |
2013 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400022 |
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