SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION

SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION

Spinel LiFe xCo2-xO4 samples with 0.25≤x≤1 were synthesized by the sol-gel Pechini method at 300ºC in order to study the impact on their structural and electrochemical properties due to the substitution of Co by Fe. The specific capacity for lithium insertion into the electrode m...

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Main Authors: MUCHNICK,NICOLE, HERRERA,FRANCISCO, ALBURQUENQUE,DANIELA, PASTENE,RUBEN, ORTIZ,JUAN, GAUTIER,JUAN LUIS
Language:English
Published: Sociedad Chilena de Química 2013
Subjects:
Lithium- Ferrites
spinels
diffusion coefficient
Li-ion batteries
sol-gel
Online Access:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400022
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spelling oai:scielo:S0717-970720130004000222014-09-02SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTIONMUCHNICK,NICOLEHERRERA,FRANCISCOALBURQUENQUE,DANIELAPASTENE,RUBENORTIZ,JUANGAUTIER,JUAN LUIS Lithium- Ferrites spinels diffusion coefficient Li-ion batteries sol-gel Spinel LiFe xCo2-xO4 samples with 0.25≤x≤1 were synthesized by the sol-gel Pechini method at 300ºC in order to study the impact on their structural and electrochemical properties due to the substitution of Co by Fe. The specific capacity for lithium insertion into the electrode materials depend on lithium diffusion coefficient DLi which in turn depends on the Fe³+/(Fe³++Co³+ +Co4+) octahedral cationic ratio.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400022en10.4067/S0717-97072013000400022
institution Scielo Chile
collection Scielo Chile
language English
topic Lithium- Ferrites
spinels
diffusion coefficient
Li-ion batteries
sol-gel
spellingShingle Lithium- Ferrites
spinels
diffusion coefficient
Li-ion batteries
sol-gel
MUCHNICK,NICOLE
HERRERA,FRANCISCO
ALBURQUENQUE,DANIELA
PASTENE,RUBEN
ORTIZ,JUAN
GAUTIER,JUAN LUIS
SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
description Spinel LiFe xCo2-xO4 samples with 0.25≤x≤1 were synthesized by the sol-gel Pechini method at 300ºC in order to study the impact on their structural and electrochemical properties due to the substitution of Co by Fe. The specific capacity for lithium insertion into the electrode materials depend on lithium diffusion coefficient DLi which in turn depends on the Fe³+/(Fe³++Co³+ +Co4+) octahedral cationic ratio.
author MUCHNICK,NICOLE
HERRERA,FRANCISCO
ALBURQUENQUE,DANIELA
PASTENE,RUBEN
ORTIZ,JUAN
GAUTIER,JUAN LUIS
author_facet MUCHNICK,NICOLE
HERRERA,FRANCISCO
ALBURQUENQUE,DANIELA
PASTENE,RUBEN
ORTIZ,JUAN
GAUTIER,JUAN LUIS
author_sort MUCHNICK,NICOLE
title SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
title_short SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
title_full SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
title_fullStr SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
title_full_unstemmed SPINEL LiFe xCo2-xO4 (0.25 ≤ x ≤ 1) AS CATHODES IN LITHIUM BATTERIES: RELATIONSHIP BETWEEN IONIC DISTRIBUTION AND LITHIUM ION INSERTION
title_sort spinel life xco2-xo4 (0.25 ≤ x ≤ 1) as cathodes in lithium batteries: relationship between ionic distribution and lithium ion insertion
publisher Sociedad Chilena de Química
publishDate 2013
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400022
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AT herrerafrancisco spinellifexco2xo40258804x88041ascathodesinlithiumbatteriesrelationshipbetweenionicdistributionandlithiumioninsertion
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