DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE

As (III) was determined by differential pulse polarography (DPP) in 1 mol L-1 HCl as supporting electrolyte. For quantification, the -0.35 V peak (versus Ag/ AgCl) was chosen. The obtained detection and quantification limits were 2.7 (3 SD) and 8.9 (10 SD) μg L-1 respectively. The method wa...

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Autores principales: GAMBOA,J.C.M, CORNEJO,L, ACARAPI,J, SQUELLA,J. A
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400028
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spelling oai:scielo:S0717-970720130004000282014-09-02DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILEGAMBOA,J.C.MCORNEJO,LACARAPI,JSQUELLA,J. A Arsenic (III) surface water differential pulse polarography As (III) was determined by differential pulse polarography (DPP) in 1 mol L-1 HCl as supporting electrolyte. For quantification, the -0.35 V peak (versus Ag/ AgCl) was chosen. The obtained detection and quantification limits were 2.7 (3 SD) and 8.9 (10 SD) μg L-1 respectively. The method was used for the determination of As (III) on surface water samples from Camarones River, located in Camarones area, province of Arica, Chile (this area's water contain high levels of salinity). The results indicate that the proposed methodology is a suitable analytical alternative for As determination in natural waters with high levels of dissolved salts, as the waters of Camarones River. The method is not time consuming, nor tedious no prior treatment of the sample is required. The results show that As (III) concentrations in waters of Camarones River are about 10 times higher than the guide values established by WHO for water intended for human consumption.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400028en10.4067/S0717-97072013000400028
institution Scielo Chile
collection Scielo Chile
language English
topic Arsenic (III)
surface water
differential pulse polarography
spellingShingle Arsenic (III)
surface water
differential pulse polarography
GAMBOA,J.C.M
CORNEJO,L
ACARAPI,J
SQUELLA,J. A
DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE
description As (III) was determined by differential pulse polarography (DPP) in 1 mol L-1 HCl as supporting electrolyte. For quantification, the -0.35 V peak (versus Ag/ AgCl) was chosen. The obtained detection and quantification limits were 2.7 (3 SD) and 8.9 (10 SD) μg L-1 respectively. The method was used for the determination of As (III) on surface water samples from Camarones River, located in Camarones area, province of Arica, Chile (this area's water contain high levels of salinity). The results indicate that the proposed methodology is a suitable analytical alternative for As determination in natural waters with high levels of dissolved salts, as the waters of Camarones River. The method is not time consuming, nor tedious no prior treatment of the sample is required. The results show that As (III) concentrations in waters of Camarones River are about 10 times higher than the guide values established by WHO for water intended for human consumption.
author GAMBOA,J.C.M
CORNEJO,L
ACARAPI,J
SQUELLA,J. A
author_facet GAMBOA,J.C.M
CORNEJO,L
ACARAPI,J
SQUELLA,J. A
author_sort GAMBOA,J.C.M
title DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE
title_short DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE
title_full DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE
title_fullStr DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE
title_full_unstemmed DETERMINATION OF ARSENIC (III) BY DIFFERENTIAL PULSE POLAROGRAPHY IN THE WATERS OF CAMARONES AREA, CHILE
title_sort determination of arsenic (iii) by differential pulse polarography in the waters of camarones area, chile
publisher Sociedad Chilena de Química
publishDate 2013
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400028
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