BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV

The blending behaviour of binary systems formed by the polymer component poly(N-vinyl-2-pyrrolidone) (PVP) and the low molecular weight compounds 4,4'-biphenol (44BP) and 2,2'-biphenol (22BP) was studied. The blends were characterized in the entire composition range by Differential Scannin...

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Autores principales:	GATICA,NICOLÁS, SOTO,LESLIE, MORAGA,CONSTANZA, VERGARA,LORETO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Materias:	Polymer blends poly (N-vinyl-2-pyrrolidone) 4,4'-biphenol 2,2'-biphenol hydrogen bond low molecular weight compounds
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400032
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spelling	oai:scielo:S0717-970720130004000322014-09-02BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IVGATICA,NICOLÁSSOTO,LESLIEMORAGA,CONSTANZAVERGARA,LORETO Polymer blends poly (N-vinyl-2-pyrrolidone) 4,4'-biphenol 2,2'-biphenol hydrogen bond low molecular weight compounds The blending behaviour of binary systems formed by the polymer component poly(N-vinyl-2-pyrrolidone) (PVP) and the low molecular weight compounds 4,4'-biphenol (44BP) and 2,2'-biphenol (22BP) was studied. The blends were characterized in the entire composition range by Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), and Scanning Electron Microscopy (SEM). Both, the glass transition temperature (Tg) and the melting point (Tm) of the pure components were affected as a consequence of the blending process. It was observed miscibility between the components in both blends and a higher interaction degree in the blend containing 44BP. FTIR analysis detected the hydrogen bonding as intermolecular interaction responsible of the observed miscibility, by means of the variation in the wave number corresponding to the stretching vibration of PVP carbonyl group. TGA and SEM analyses provided coherent and complementary results with both DSC and FTIR.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400032en10.4067/S0717-97072013000400032
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Polymer blends poly (N-vinyl-2-pyrrolidone) 4,4'-biphenol 2,2'-biphenol hydrogen bond low molecular weight compounds
spellingShingle	Polymer blends poly (N-vinyl-2-pyrrolidone) 4,4'-biphenol 2,2'-biphenol hydrogen bond low molecular weight compounds GATICA,NICOLÁS SOTO,LESLIE MORAGA,CONSTANZA VERGARA,LORETO BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV
description	The blending behaviour of binary systems formed by the polymer component poly(N-vinyl-2-pyrrolidone) (PVP) and the low molecular weight compounds 4,4'-biphenol (44BP) and 2,2'-biphenol (22BP) was studied. The blends were characterized in the entire composition range by Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), and Scanning Electron Microscopy (SEM). Both, the glass transition temperature (Tg) and the melting point (Tm) of the pure components were affected as a consequence of the blending process. It was observed miscibility between the components in both blends and a higher interaction degree in the blend containing 44BP. FTIR analysis detected the hydrogen bonding as intermolecular interaction responsible of the observed miscibility, by means of the variation in the wave number corresponding to the stretching vibration of PVP carbonyl group. TGA and SEM analyses provided coherent and complementary results with both DSC and FTIR.
author	GATICA,NICOLÁS SOTO,LESLIE MORAGA,CONSTANZA VERGARA,LORETO
author_facet	GATICA,NICOLÁS SOTO,LESLIE MORAGA,CONSTANZA VERGARA,LORETO
author_sort	GATICA,NICOLÁS
title	BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV
title_short	BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV
title_full	BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV
title_fullStr	BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV
title_full_unstemmed	BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV
title_sort	blends of poly(n-vinyl-2-pyrrolidone) and dihydric phenols: thermal and infrared spectroscopic studies. part iv
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400032
work_keys_str_mv	AT gaticanicolas blendsofpolynvinyl2pyrrolidoneanddihydricphenolsthermalandinfraredspectroscopicstudiespartiv AT sotoleslie blendsofpolynvinyl2pyrrolidoneanddihydricphenolsthermalandinfraredspectroscopicstudiespartiv AT moragaconstanza blendsofpolynvinyl2pyrrolidoneanddihydricphenolsthermalandinfraredspectroscopicstudiespartiv AT vergaraloreto blendsofpolynvinyl2pyrrolidoneanddihydricphenolsthermalandinfraredspectroscopicstudiespartiv
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BLENDS OF POLY(N-VINYL-2-PYRROLIDONE) AND DIHYDRIC PHENOLS: THERMAL AND INFRARED SPECTROSCOPIC STUDIES. PART IV

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