DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS

In this work the adsorption of 4,6-dimethyldibenzothiophene (4,6-DMDBT) on different supports (SiO2, Al2O3, zeolite 4A, zeolite 13X, natural zeolite, and activated carbon), incorporating on its surface different first series transition metal oxides at different content, was studied. The results indi...

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Autores principales: APARICIO,F, CAMÚ,E, VILLARROEL,M, ESCALONA,N, BAEZA,P
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400034
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spelling oai:scielo:S0717-970720130004000342014-09-02DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTSAPARICIO,FCAMÚ,EVILLARROEL,MESCALONA,NBAEZA,P Adsorption supports transitions metals 4,6-Dimethyldibenzothiophene In this work the adsorption of 4,6-dimethyldibenzothiophene (4,6-DMDBT) on different supports (SiO2, Al2O3, zeolite 4A, zeolite 13X, natural zeolite, and activated carbon), incorporating on its surface different first series transition metal oxides at different content, was studied. The results indicate that the activated carbon presents a higher adsorption capacity than the other supports studied, which it is assumed to the large number of functional groups present on its surface. The incorporation of the first series transition metal oxides on support, induces in some cases the increase of the adsorption capacities of 4,6-DMDBT and these adsorptions capacities depend on metal content. Finally, the desulfurization by adsorption represents an alternative tool for the elimination of refractory sulfur compounds.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400034en10.4067/S0717-97072013000400034
institution Scielo Chile
collection Scielo Chile
language English
topic Adsorption
supports
transitions metals
4,6-Dimethyldibenzothiophene
spellingShingle Adsorption
supports
transitions metals
4,6-Dimethyldibenzothiophene
APARICIO,F
CAMÚ,E
VILLARROEL,M
ESCALONA,N
BAEZA,P
DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS
description In this work the adsorption of 4,6-dimethyldibenzothiophene (4,6-DMDBT) on different supports (SiO2, Al2O3, zeolite 4A, zeolite 13X, natural zeolite, and activated carbon), incorporating on its surface different first series transition metal oxides at different content, was studied. The results indicate that the activated carbon presents a higher adsorption capacity than the other supports studied, which it is assumed to the large number of functional groups present on its surface. The incorporation of the first series transition metal oxides on support, induces in some cases the increase of the adsorption capacities of 4,6-DMDBT and these adsorptions capacities depend on metal content. Finally, the desulfurization by adsorption represents an alternative tool for the elimination of refractory sulfur compounds.
author APARICIO,F
CAMÚ,E
VILLARROEL,M
ESCALONA,N
BAEZA,P
author_facet APARICIO,F
CAMÚ,E
VILLARROEL,M
ESCALONA,N
BAEZA,P
author_sort APARICIO,F
title DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS
title_short DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS
title_full DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS
title_fullStr DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS
title_full_unstemmed DEEP DESULFURIZATION BY ADSORPTION OF 4,6-DIMETHYLDIBENZOTHIOPHENE, STUDY OF ADSORPTION ON DIFFERENT TRANSITION METAL OXIDES AND SUPPORTS
title_sort deep desulfurization by adsorption of 4,6-dimethyldibenzothiophene, study of adsorption on different transition metal oxides and supports
publisher Sociedad Chilena de Química
publishDate 2013
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400034
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AT camue deepdesulfurizationbyadsorptionof46dimethyldibenzothiophenestudyofadsorptionondifferenttransitionmetaloxidesandsupports
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AT escalonan deepdesulfurizationbyadsorptionof46dimethyldibenzothiophenestudyofadsorptionondifferenttransitionmetaloxidesandsupports
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