EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES

The influence of fluorine concentration on the synergism between Co/γ-Al2O3 and MoAy-Al2O3 stacked beds separated by 3-mm of γ-Al2O3Fx (x = 0 - 2.5%), in the hydrodesulphurization of refractory molecules contained in gasoil, under operating conditions similar to those of industry,...

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Autores principales:	MÉNDEZ,A, VILLARROEL,M, CAMÚ,E, GIL-LLAMBÍAS,F. J, ÁVILA,P, BAEZA,P
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Materias:	Hydrodesulphurization Fluorine Stacked Bed Synergism
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400036
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spelling	oai:scielo:S0717-970720130004000362014-09-02EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULESMÉNDEZ,AVILLARROEL,MCAMÚ,EGIL-LLAMBÍAS,F. JÁVILA,PBAEZA,P Hydrodesulphurization Fluorine Stacked Bed Synergism The influence of fluorine concentration on the synergism between Co/γ-Al2O3 and MoAy-Al2O3 stacked beds separated by 3-mm of γ-Al2O3Fx (x = 0 - 2.5%), in the hydrodesulphurization of refractory molecules contained in gasoil, under operating conditions similar to those of industry, was studied. The results shown, that the synergism increases with F content, reaching a maximum at 0.8% of fluorine, which it is related to changes in zero point of charge (ZPC) and acid strength, due to the incorporation of fluorine. The conversion of most refractory molecule reported is favoured by fluorine.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400036en10.4067/S0717-97072013000400036
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Hydrodesulphurization Fluorine Stacked Bed Synergism
spellingShingle	Hydrodesulphurization Fluorine Stacked Bed Synergism MÉNDEZ,A VILLARROEL,M CAMÚ,E GIL-LLAMBÍAS,F. J ÁVILA,P BAEZA,P EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES
description	The influence of fluorine concentration on the synergism between Co/γ-Al2O3 and MoAy-Al2O3 stacked beds separated by 3-mm of γ-Al2O3Fx (x = 0 - 2.5%), in the hydrodesulphurization of refractory molecules contained in gasoil, under operating conditions similar to those of industry, was studied. The results shown, that the synergism increases with F content, reaching a maximum at 0.8% of fluorine, which it is related to changes in zero point of charge (ZPC) and acid strength, due to the incorporation of fluorine. The conversion of most refractory molecule reported is favoured by fluorine.
author	MÉNDEZ,A VILLARROEL,M CAMÚ,E GIL-LLAMBÍAS,F. J ÁVILA,P BAEZA,P
author_facet	MÉNDEZ,A VILLARROEL,M CAMÚ,E GIL-LLAMBÍAS,F. J ÁVILA,P BAEZA,P
author_sort	MÉNDEZ,A
title	EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES
title_short	EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES
title_full	EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES
title_fullStr	EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES
title_full_unstemmed	EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES
title_sort	effect of fluorine in the synergism co-mo via hydrogen spillover on the hydrodesul-phurization of refractory molecules
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400036
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EFFECT OF FLUORINE IN THE SYNERGISM Co-Mo VIA HYDROGEN SPILLOVER ON THE HYDRODESUL-PHURIZATION OF REFRACTORY MOLECULES

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