AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactio...
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Sociedad Chilena de Química
2013
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Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052 |
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oai:scielo:S0717-970720130004000522014-09-02AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTSAPANDA,BZOLEZZI,SVALDEBENITO,GCÁCERES-VÁSQUEZ,JMOYA,S. A.AGUIRRE,PThe catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052en10.4067/S0717-97072013000400052 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
description |
The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure. |
author |
APANDA,B ZOLEZZI,S VALDEBENITO,G CÁCERES-VÁSQUEZ,J MOYA,S. A. AGUIRRE,P |
spellingShingle |
APANDA,B ZOLEZZI,S VALDEBENITO,G CÁCERES-VÁSQUEZ,J MOYA,S. A. AGUIRRE,P AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS |
author_facet |
APANDA,B ZOLEZZI,S VALDEBENITO,G CÁCERES-VÁSQUEZ,J MOYA,S. A. AGUIRRE,P |
author_sort |
APANDA,B |
title |
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS |
title_short |
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS |
title_full |
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS |
title_fullStr |
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS |
title_full_unstemmed |
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS |
title_sort |
aminocarbonylation reaction using palladium complexes containing phosphorus-nitrogen ligands as catalysts |
publisher |
Sociedad Chilena de Química |
publishDate |
2013 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052 |
work_keys_str_mv |
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_version_ |
1718445505488355328 |