AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS

The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactio...

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Autores principales:	APANDA,B, ZOLEZZI,S, VALDEBENITO,G, CÁCERES-VÁSQUEZ,J, MOYA,S. A., AGUIRRE,P
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052
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spelling	oai:scielo:S0717-970720130004000522014-09-02AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTSAPANDA,BZOLEZZI,SVALDEBENITO,GCÁCERES-VÁSQUEZ,JMOYA,S. A.AGUIRRE,PThe catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052en10.4067/S0717-97072013000400052
institution	Scielo Chile
collection	Scielo Chile
language	English
description	The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure.
author	APANDA,B ZOLEZZI,S VALDEBENITO,G CÁCERES-VÁSQUEZ,J MOYA,S. A. AGUIRRE,P
spellingShingle	APANDA,B ZOLEZZI,S VALDEBENITO,G CÁCERES-VÁSQUEZ,J MOYA,S. A. AGUIRRE,P AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
author_facet	APANDA,B ZOLEZZI,S VALDEBENITO,G CÁCERES-VÁSQUEZ,J MOYA,S. A. AGUIRRE,P
author_sort	APANDA,B
title	AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_short	AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_full	AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_fullStr	AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_full_unstemmed	AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_sort	aminocarbonylation reaction using palladium complexes containing phosphorus-nitrogen ligands as catalysts
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052
work_keys_str_mv	AT apandab aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts AT zolezzis aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts AT valdebenitog aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts AT caceresvasquezj aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts AT moyasa aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts AT aguirrep aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
_version_	1718445505488355328

AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS

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