AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS

The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactio...

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Autores principales: APANDA,B, ZOLEZZI,S, VALDEBENITO,G, CÁCERES-VÁSQUEZ,J, MOYA,S. A., AGUIRRE,P
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052
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spelling oai:scielo:S0717-970720130004000522014-09-02AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTSAPANDA,BZOLEZZI,SVALDEBENITO,GCÁCERES-VÁSQUEZ,JMOYA,S. A.AGUIRRE,PThe catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052en10.4067/S0717-97072013000400052
institution Scielo Chile
collection Scielo Chile
language English
description The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure.
author APANDA,B
ZOLEZZI,S
VALDEBENITO,G
CÁCERES-VÁSQUEZ,J
MOYA,S. A.
AGUIRRE,P
spellingShingle APANDA,B
ZOLEZZI,S
VALDEBENITO,G
CÁCERES-VÁSQUEZ,J
MOYA,S. A.
AGUIRRE,P
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
author_facet APANDA,B
ZOLEZZI,S
VALDEBENITO,G
CÁCERES-VÁSQUEZ,J
MOYA,S. A.
AGUIRRE,P
author_sort APANDA,B
title AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_short AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_full AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_fullStr AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_full_unstemmed AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
title_sort aminocarbonylation reaction using palladium complexes containing phosphorus-nitrogen ligands as catalysts
publisher Sociedad Chilena de Química
publishDate 2013
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400052
work_keys_str_mv AT apandab aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
AT zolezzis aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
AT valdebenitog aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
AT caceresvasquezj aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
AT moyasa aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
AT aguirrep aminocarbonylationreactionusingpalladiumcomplexescontainingphosphorusnitrogenligandsascatalysts
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