THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION

The corrosion behaviour of mild steel in 1.0 M HCl solution containing different concentrations of Calcein at different temperatures was investigated using the impedance, potentiodynamic polarization and linear polarization techniques. Long term tests were accomplished by hydrogen gas evolution and...

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Autores principales: ÖZKIR,DEMET, BAYOL,EMEL, GÜRTEN,A. ALI, SÜRME,YAVUZ
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
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EIS
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400056
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spelling oai:scielo:S0717-970720130004000562014-09-02THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTIONÖZKIR,DEMETBAYOL,EMELGÜRTEN,A. ALISÜRME,YAVUZ Mild Steel Polarization EIS Acid Corrosion Calcein The corrosion behaviour of mild steel in 1.0 M HCl solution containing different concentrations of Calcein at different temperatures was investigated using the impedance, potentiodynamic polarization and linear polarization techniques. Long term tests were accomplished by hydrogen gas evolution and impedance measurements. The results showed that inhibition efficiency has increased with the inhibitor concentration and temperature increment. The adsorption of the inhibitor on the mild steel surface obeyed the Langmuir isotherm. Activation energy values at concentrations of Calcein were lower than that of uninhibited system. The thermodynamic parameters of adsorption deduced reveal a strong interaction of Calcein on the mild steel surface.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400056en10.4067/S0717-97072013000400056
institution Scielo Chile
collection Scielo Chile
language English
topic Mild Steel
Polarization
EIS
Acid Corrosion
Calcein
spellingShingle Mild Steel
Polarization
EIS
Acid Corrosion
Calcein
ÖZKIR,DEMET
BAYOL,EMEL
GÜRTEN,A. ALI
SÜRME,YAVUZ
THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
description The corrosion behaviour of mild steel in 1.0 M HCl solution containing different concentrations of Calcein at different temperatures was investigated using the impedance, potentiodynamic polarization and linear polarization techniques. Long term tests were accomplished by hydrogen gas evolution and impedance measurements. The results showed that inhibition efficiency has increased with the inhibitor concentration and temperature increment. The adsorption of the inhibitor on the mild steel surface obeyed the Langmuir isotherm. Activation energy values at concentrations of Calcein were lower than that of uninhibited system. The thermodynamic parameters of adsorption deduced reveal a strong interaction of Calcein on the mild steel surface.
author ÖZKIR,DEMET
BAYOL,EMEL
GÜRTEN,A. ALI
SÜRME,YAVUZ
author_facet ÖZKIR,DEMET
BAYOL,EMEL
GÜRTEN,A. ALI
SÜRME,YAVUZ
author_sort ÖZKIR,DEMET
title THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
title_short THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
title_full THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
title_fullStr THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
title_full_unstemmed THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
title_sort thermodynamic study and electrochemical investigation of calcein as corrosion inhibitor for mild steel in hydrochloric acid solution
publisher Sociedad Chilena de Química
publishDate 2013
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400056
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AT bayolemel thermodynamicstudyandelectrochemicalinvestigationofcalceinascorrosioninhibitorformildsteelinhydrochloricacidsolution
AT gurtenaali thermodynamicstudyandelectrochemicalinvestigationofcalceinascorrosioninhibitorformildsteelinhydrochloricacidsolution
AT surmeyavuz thermodynamicstudyandelectrochemicalinvestigationofcalceinascorrosioninhibitorformildsteelinhydrochloricacidsolution
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