THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION
The corrosion behaviour of mild steel in 1.0 M HCl solution containing different concentrations of Calcein at different temperatures was investigated using the impedance, potentiodynamic polarization and linear polarization techniques. Long term tests were accomplished by hydrogen gas evolution and...
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Sociedad Chilena de Química
2013
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oai:scielo:S0717-970720130004000562014-09-02THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTIONÖZKIR,DEMETBAYOL,EMELGÜRTEN,A. ALISÜRME,YAVUZ Mild Steel Polarization EIS Acid Corrosion Calcein The corrosion behaviour of mild steel in 1.0 M HCl solution containing different concentrations of Calcein at different temperatures was investigated using the impedance, potentiodynamic polarization and linear polarization techniques. Long term tests were accomplished by hydrogen gas evolution and impedance measurements. The results showed that inhibition efficiency has increased with the inhibitor concentration and temperature increment. The adsorption of the inhibitor on the mild steel surface obeyed the Langmuir isotherm. Activation energy values at concentrations of Calcein were lower than that of uninhibited system. The thermodynamic parameters of adsorption deduced reveal a strong interaction of Calcein on the mild steel surface.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400056en10.4067/S0717-97072013000400056 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Mild Steel Polarization EIS Acid Corrosion Calcein |
spellingShingle |
Mild Steel Polarization EIS Acid Corrosion Calcein ÖZKIR,DEMET BAYOL,EMEL GÜRTEN,A. ALI SÜRME,YAVUZ THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION |
description |
The corrosion behaviour of mild steel in 1.0 M HCl solution containing different concentrations of Calcein at different temperatures was investigated using the impedance, potentiodynamic polarization and linear polarization techniques. Long term tests were accomplished by hydrogen gas evolution and impedance measurements. The results showed that inhibition efficiency has increased with the inhibitor concentration and temperature increment. The adsorption of the inhibitor on the mild steel surface obeyed the Langmuir isotherm. Activation energy values at concentrations of Calcein were lower than that of uninhibited system. The thermodynamic parameters of adsorption deduced reveal a strong interaction of Calcein on the mild steel surface. |
author |
ÖZKIR,DEMET BAYOL,EMEL GÜRTEN,A. ALI SÜRME,YAVUZ |
author_facet |
ÖZKIR,DEMET BAYOL,EMEL GÜRTEN,A. ALI SÜRME,YAVUZ |
author_sort |
ÖZKIR,DEMET |
title |
THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION |
title_short |
THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION |
title_full |
THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION |
title_fullStr |
THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION |
title_full_unstemmed |
THERMODYNAMIC STUDY AND ELECTROCHEMICAL INVESTIGATION OF CALCEIN AS CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID SOLUTION |
title_sort |
thermodynamic study and electrochemical investigation of calcein as corrosion inhibitor for mild steel in hydrochloric acid solution |
publisher |
Sociedad Chilena de Química |
publishDate |
2013 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400056 |
work_keys_str_mv |
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