AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS

The chloromethylation of aromatic hydrocarbons proceeded efficiently using the reusable imidazolium-based ionic liquid as promoter. Mild reaction conditions, enhanced rates, improved yields, recyclability of ionic liquids, and reagents' reactivity which is different from that in conventional or...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	WANG,YUN, XI,YANLI
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2013
Materias:	Ionic liquid Chloromethylation Aromatic hydrocarbons DFT Solvent effects
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400063
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072013000400063
record_format	dspace
spelling	oai:scielo:S0717-970720130004000632014-09-02AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONSWANG,YUNXI,YANLI Ionic liquid Chloromethylation Aromatic hydrocarbons DFT Solvent effects The chloromethylation of aromatic hydrocarbons proceeded efficiently using the reusable imidazolium-based ionic liquid as promoter. Mild reaction conditions, enhanced rates, improved yields, recyclability of ionic liquids, and reagents' reactivity which is different from that in conventional organic solvents are the remarkable features observed in ionic liquids. The ionic liquids were recycled in three subsequent runs with no decrease in activity. In addition, the results of calculations with the Gaussian 98 suite of program are in good accordance with the experimental outcomes.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.58 n.4 20132013-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400063en10.4067/S0717-97072013000400063
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Ionic liquid Chloromethylation Aromatic hydrocarbons DFT Solvent effects
spellingShingle	Ionic liquid Chloromethylation Aromatic hydrocarbons DFT Solvent effects WANG,YUN XI,YANLI AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS
description	The chloromethylation of aromatic hydrocarbons proceeded efficiently using the reusable imidazolium-based ionic liquid as promoter. Mild reaction conditions, enhanced rates, improved yields, recyclability of ionic liquids, and reagents' reactivity which is different from that in conventional organic solvents are the remarkable features observed in ionic liquids. The ionic liquids were recycled in three subsequent runs with no decrease in activity. In addition, the results of calculations with the Gaussian 98 suite of program are in good accordance with the experimental outcomes.
author	WANG,YUN XI,YANLI
author_facet	WANG,YUN XI,YANLI
author_sort	WANG,YUN
title	AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS
title_short	AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS
title_full	AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS
title_fullStr	AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS
title_full_unstemmed	AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS
title_sort	experimental and theoretical study on imidazolium-based ionic liquid promoted chloromethylation of aromatic hydrocarbons
publisher	Sociedad Chilena de Química
publishDate	2013
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000400063
work_keys_str_mv	AT wangyun anexperimentalandtheoreticalstudyonimidazoliumbasedionicliquidpromotedchloromethylationofaromatichydrocarbons AT xiyanli anexperimentalandtheoreticalstudyonimidazoliumbasedionicliquidpromotedchloromethylationofaromatichydrocarbons AT wangyun experimentalandtheoreticalstudyonimidazoliumbasedionicliquidpromotedchloromethylationofaromatichydrocarbons AT xiyanli experimentalandtheoreticalstudyonimidazoliumbasedionicliquidpromotedchloromethylationofaromatichydrocarbons
_version_	1718445507464921088

AN EXPERIMENTAL AND THEORETICAL STUDY ON IMIDAZOLIUM-BASED IONIC LIQUID PROMOTED CHLOROMETHYLATION OF AROMATIC HYDROCARBONS

Ejemplares similares