SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS

Aminomethylated polystyrene (PSCH2-NH2) reacts with 3-ethoxysalicylaldehyde in equimolar amounts to produce monobasic bidentate (ON donor) polystyrene-anchored Schiff base (PS-LH). The latter upon refluxing with metal the ions in 1:2 molar ratios gives polystyrene-anchored coordination compounds of...

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Autores principales:	KUMAR,DINESH, KUMAR GUPTA,PRAVEEN, SYAMAL,ARUN
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2014
Materias:	polystyrene-anchored Schiff base coordination compounds diamagnetic magnetically dilute
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000100004
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spelling	oai:scielo:S0717-970720140001000042015-11-12SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONSKUMAR,DINESHKUMAR GUPTA,PRAVEENSYAMAL,ARUN polystyrene-anchored Schiff base coordination compounds diamagnetic magnetically dilute Aminomethylated polystyrene (PSCH2-NH2) reacts with 3-ethoxysalicylaldehyde in equimolar amounts to produce monobasic bidentate (ON donor) polystyrene-anchored Schiff base (PS-LH). The latter upon refluxing with metal the ions in 1:2 molar ratios gives polystyrene-anchored coordination compounds of types: [PSCH2-LM(OAc)(DMF)] (where M = Cd, Co, Cu, Zn, UO2), [PSCH2-LNi(OAc)(DMF)3], [PSCH2-LFeCl2(DMF)2], [PSCH2-LMCl(CH3OH)] (where M = Cd, Zn) and [PSCH2-LMoO2(acac)]. The polystyrene-anchored compounds have been characterized on the basis of elemental analyses, spectral (IR, reflectance, ESR) and magnetic susceptibility measurements. The polystyrene-anchored Co(II), Cu(II), Ni(II) and Fe(III) compounds are paramagnetic, while others are diamagnetic. Co(II) and Cu(II) compounds are square-planar; Zn(II) and Cd(II) compounds are tetrahedral; Ni(II), Fe(III), MoO2(VI) and UO2(VI) compounds are octahedral.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.59 n.1 20142014-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000100004en10.4067/S0717-97072014000100004
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	polystyrene-anchored Schiff base coordination compounds diamagnetic magnetically dilute
spellingShingle	polystyrene-anchored Schiff base coordination compounds diamagnetic magnetically dilute KUMAR,DINESH KUMAR GUPTA,PRAVEEN SYAMAL,ARUN SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS
description	Aminomethylated polystyrene (PSCH2-NH2) reacts with 3-ethoxysalicylaldehyde in equimolar amounts to produce monobasic bidentate (ON donor) polystyrene-anchored Schiff base (PS-LH). The latter upon refluxing with metal the ions in 1:2 molar ratios gives polystyrene-anchored coordination compounds of types: [PSCH2-LM(OAc)(DMF)] (where M = Cd, Co, Cu, Zn, UO2), [PSCH2-LNi(OAc)(DMF)3], [PSCH2-LFeCl2(DMF)2], [PSCH2-LMCl(CH3OH)] (where M = Cd, Zn) and [PSCH2-LMoO2(acac)]. The polystyrene-anchored compounds have been characterized on the basis of elemental analyses, spectral (IR, reflectance, ESR) and magnetic susceptibility measurements. The polystyrene-anchored Co(II), Cu(II), Ni(II) and Fe(III) compounds are paramagnetic, while others are diamagnetic. Co(II) and Cu(II) compounds are square-planar; Zn(II) and Cd(II) compounds are tetrahedral; Ni(II), Fe(III), MoO2(VI) and UO2(VI) compounds are octahedral.
author	KUMAR,DINESH KUMAR GUPTA,PRAVEEN SYAMAL,ARUN
author_facet	KUMAR,DINESH KUMAR GUPTA,PRAVEEN SYAMAL,ARUN
author_sort	KUMAR,DINESH
title	SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS
title_short	SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS
title_full	SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS
title_fullStr	SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS
title_full_unstemmed	SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS
title_sort	syntheses and structural studies on coordination compounds of polystyrene-anchored schiff base with some metal ions
publisher	Sociedad Chilena de Química
publishDate	2014
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000100004
work_keys_str_mv	AT kumardinesh synthesesandstructuralstudiesoncoordinationcompoundsofpolystyreneanchoredschiffbasewithsomemetalions AT kumarguptapraveen synthesesandstructuralstudiesoncoordinationcompoundsofpolystyreneanchoredschiffbasewithsomemetalions AT syamalarun synthesesandstructuralstudiesoncoordinationcompoundsofpolystyreneanchoredschiffbasewithsomemetalions
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SYNTHESES AND STRUCTURAL STUDIES ON COORDINATION COMPOUNDS OF POLYSTYRENE-ANCHORED SCHIFF BASE WITH SOME METAL IONS

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