SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS

The organometallic derivatives of poly(styrene-co-4vinylpyridine), PS-co-4-PVP, of the general formula: {[CH2CH(C6H J)]0.1[CH2CH(C5H4NMLn)]0.9}n; MLn = W(CO)5 , (1), CpRu(PPh3)2 (2), CpFe(dppe) (3), Cp2TiCl (4) and CH3-C5H4-Mn(CO)2 (5) were prepared from the respective organometallic and the '...

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Autores principales:	DÍAZ,CARLOS, VALENZUELA,MARÍA LUISA, CARRIEDO,GABINO, YUTRONIC,NICOLAS
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2014
Materias:	Micro and nanostructured materials metal oxide solid-state nanoparticles
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000200008
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spelling	oai:scielo:S0717-970720140002000082014-11-05SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORSDÍAZ,CARLOSVALENZUELA,MARÍA LUISACARRIEDO,GABINOYUTRONIC,NICOLAS Micro and nanostructured materials metal oxide solid-state nanoparticles The organometallic derivatives of poly(styrene-co-4vinylpyridine), PS-co-4-PVP, of the general formula: {[CH2CH(C6H J)]0.1[CH2CH(C5H4NMLn)]0.9}n; MLn = W(CO)5 , (1), CpRu(PPh3)2 (2), CpFe(dppe) (3), Cp2TiCl (4) and CH3-C5H4-Mn(CO)2 (5) were prepared from the respective organometallic and the ' co-polymer {[CH2CH(C6H5)]0.1[CH2CH(C5H4N]0.9}n. The solid state pyrolysis of these derivatives under air and at 800 °C give rise to micro and nanostructured powder metal oxides WO3, RuO2, TiO2 Mn2O3 and the iron (III) phosphate (FePO4) in the case of the iron precursor. The pyrolytic products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive X-ray scattering (EDX) and infrared spectroscopy (IR). From the TG (thermal gravimetric) and DSC (differential scanning calorimetry) data a possible mechanism for the formation of the solid nanostructured materials is discussed. The method appears to be a reliable and general way to obtain nanostructured metal oxide in solid-state which could be potentially and easily incorporated in solid-state electronics, catalysts and sensor devices.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.59 n.2 20142014-07-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000200008en10.4067/S0717-97072014000200008
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Micro and nanostructured materials metal oxide solid-state nanoparticles
spellingShingle	Micro and nanostructured materials metal oxide solid-state nanoparticles DÍAZ,CARLOS VALENZUELA,MARÍA LUISA CARRIEDO,GABINO YUTRONIC,NICOLAS SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS
description	The organometallic derivatives of poly(styrene-co-4vinylpyridine), PS-co-4-PVP, of the general formula: {[CH2CH(C6H J)]0.1[CH2CH(C5H4NMLn)]0.9}n; MLn = W(CO)5 , (1), CpRu(PPh3)2 (2), CpFe(dppe) (3), Cp2TiCl (4) and CH3-C5H4-Mn(CO)2 (5) were prepared from the respective organometallic and the ' co-polymer {[CH2CH(C6H5)]0.1[CH2CH(C5H4N]0.9}n. The solid state pyrolysis of these derivatives under air and at 800 °C give rise to micro and nanostructured powder metal oxides WO3, RuO2, TiO2 Mn2O3 and the iron (III) phosphate (FePO4) in the case of the iron precursor. The pyrolytic products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive X-ray scattering (EDX) and infrared spectroscopy (IR). From the TG (thermal gravimetric) and DSC (differential scanning calorimetry) data a possible mechanism for the formation of the solid nanostructured materials is discussed. The method appears to be a reliable and general way to obtain nanostructured metal oxide in solid-state which could be potentially and easily incorporated in solid-state electronics, catalysts and sensor devices.
author	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA CARRIEDO,GABINO YUTRONIC,NICOLAS
author_facet	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA CARRIEDO,GABINO YUTRONIC,NICOLAS
author_sort	DÍAZ,CARLOS
title	SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS
title_short	SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS
title_full	SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS
title_fullStr	SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS
title_full_unstemmed	SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS
title_sort	solid state synthesis of micro and nanostructured metal oxides using organometallic-polymers precursors
publisher	Sociedad Chilena de Química
publishDate	2014
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000200008
work_keys_str_mv	AT diazcarlos solidstatesynthesisofmicroandnanostructuredmetaloxidesusingorganometallicpolymersprecursors AT valenzuelamarialuisa solidstatesynthesisofmicroandnanostructuredmetaloxidesusingorganometallicpolymersprecursors AT carriedogabino solidstatesynthesisofmicroandnanostructuredmetaloxidesusingorganometallicpolymersprecursors AT yutronicnicolas solidstatesynthesisofmicroandnanostructuredmetaloxidesusingorganometallicpolymersprecursors
_version_	1718445516529860608

SOLID STATE SYNTHESIS OF MICRO AND NANOSTRUCTURED METAL OXIDES USING ORGANOMETALLIC-POLYMERS PRECURSORS

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