EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY

The rotating disk sorptive extraction (RDSE) technique was applied in this study to the extraction of 16 polycyclic aromatic hydrocarbons (PAHs) in real water samples. The sorptive and desorptive behavior of the analytes were studied by using a rotating disk coated with polydimethylsiloxane (PDMS) o...

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Autores principales:	CORROTEA,YANINA, SÁNCHEZ,KAREN, RUBIO,M. ANGÉLICA, RICHTER,PABLO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2014
Materias:	Rotating disk sorptive extraction Polydimethylsiloxane PAHs Water samples
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000200017
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spelling	oai:scielo:S0717-970720140002000172014-11-05EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRYCORROTEA,YANINASÁNCHEZ,KARENRUBIO,M. ANGÉLICARICHTER,PABLO Rotating disk sorptive extraction Polydimethylsiloxane PAHs Water samples The rotating disk sorptive extraction (RDSE) technique was applied in this study to the extraction of 16 polycyclic aromatic hydrocarbons (PAHs) in real water samples. The sorptive and desorptive behavior of the analytes were studied by using a rotating disk coated with polydimethylsiloxane (PDMS) on one of its surfaces. The optimal conditions for extractions of all analytes were: rotational velocity of the disk: 1250 rpm; sample volume: 20 mL; matrix modifier: 20 % MeOH and extraction time: 30 min. A desorption time of 10 min at 1250 rpm was used for the analytes using 5 mL of methanol. PAHs were measured in the extract by gas chromatography coupled to mass spectrometry (GC-MS). Under these conditions, recoveries ranging from 84 to 100 % were obtained in drinking water enriched with the analytes, and the precision, expressed as relative standard deviation, was between 2 and 20%. The detection limit of the method was between 8 and 115 ng L-1 depending on the analyte. The method was applied to the analysis of water samples obtained from a lagoon in Curauma, Chile, obtaining quantitative recoveries.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.59 n.2 20142014-07-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000200017en10.4067/S0717-97072014000200017
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Rotating disk sorptive extraction Polydimethylsiloxane PAHs Water samples
spellingShingle	Rotating disk sorptive extraction Polydimethylsiloxane PAHs Water samples CORROTEA,YANINA SÁNCHEZ,KAREN RUBIO,M. ANGÉLICA RICHTER,PABLO EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY
description	The rotating disk sorptive extraction (RDSE) technique was applied in this study to the extraction of 16 polycyclic aromatic hydrocarbons (PAHs) in real water samples. The sorptive and desorptive behavior of the analytes were studied by using a rotating disk coated with polydimethylsiloxane (PDMS) on one of its surfaces. The optimal conditions for extractions of all analytes were: rotational velocity of the disk: 1250 rpm; sample volume: 20 mL; matrix modifier: 20 % MeOH and extraction time: 30 min. A desorption time of 10 min at 1250 rpm was used for the analytes using 5 mL of methanol. PAHs were measured in the extract by gas chromatography coupled to mass spectrometry (GC-MS). Under these conditions, recoveries ranging from 84 to 100 % were obtained in drinking water enriched with the analytes, and the precision, expressed as relative standard deviation, was between 2 and 20%. The detection limit of the method was between 8 and 115 ng L-1 depending on the analyte. The method was applied to the analysis of water samples obtained from a lagoon in Curauma, Chile, obtaining quantitative recoveries.
author	CORROTEA,YANINA SÁNCHEZ,KAREN RUBIO,M. ANGÉLICA RICHTER,PABLO
author_facet	CORROTEA,YANINA SÁNCHEZ,KAREN RUBIO,M. ANGÉLICA RICHTER,PABLO
author_sort	CORROTEA,YANINA
title	EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY
title_short	EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY
title_full	EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY
title_fullStr	EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY
title_full_unstemmed	EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY
title_sort	extraction of polycyclic aromatic hydrocarbons from water samples into a rotating-disk microextractor and the subsequent determination by gas chromatography-mass spectrometry
publisher	Sociedad Chilena de Química
publishDate	2014
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000200017
work_keys_str_mv	AT corroteayanina extractionofpolycyclicaromatichydrocarbonsfromwatersamplesintoarotatingdiskmicroextractorandthesubsequentdeterminationbygaschromatographymassspectrometry AT sanchezkaren extractionofpolycyclicaromatichydrocarbonsfromwatersamplesintoarotatingdiskmicroextractorandthesubsequentdeterminationbygaschromatographymassspectrometry AT rubiomangelica extractionofpolycyclicaromatichydrocarbonsfromwatersamplesintoarotatingdiskmicroextractorandthesubsequentdeterminationbygaschromatographymassspectrometry AT richterpablo extractionofpolycyclicaromatichydrocarbonsfromwatersamplesintoarotatingdiskmicroextractorandthesubsequentdeterminationbygaschromatographymassspectrometry
_version_	1718445518045052928

EXTRACTION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM WATER SAMPLES INTO A ROTATING-DISK MICROEXTRACTOR AND THE SUBSEQUENT DETERMINATION BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY

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