SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID
A new complex [Cd(2,4-D)2(Im)2(H2O)2] with 2,4-dichlorophenoxyacetic acid (2,4-DH) and imidazole (Im) as ligands has been synthesized and characterized by elemental analysis, IR spectrometry and single-crystal X-ray diffraction. The Cd(II) atom is coordinated in a distorted octahedral geometry, whic...
Guardado en:
| Autor principal: | |
|---|---|
| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2014
|
| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000300009 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| id |
oai:scielo:S0717-97072014000300009 |
|---|---|
| record_format |
dspace |
| spelling |
oai:scielo:S0717-970720140003000092014-12-15SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACIDZHOU,YONG-HONG Crystal structure 2,4-dichlorophenoxyacetic acid Cadmium(II) complex A new complex [Cd(2,4-D)2(Im)2(H2O)2] with 2,4-dichlorophenoxyacetic acid (2,4-DH) and imidazole (Im) as ligands has been synthesized and characterized by elemental analysis, IR spectrometry and single-crystal X-ray diffraction. The Cd(II) atom is coordinated in a distorted octahedral geometry, which is defined by two O atoms from two monodentate 2,4-dichlorophenoxyacetate ligands, two N atoms from two imidazole ligands and two water molecules. Intermolecular O-H...O hydrogen bonds form chains, which are connected by N-H...O hydrogen bonds, generating a sheet structure. The molecules are further assembled by π...π stacking interactions to form a two dimensional supramolecular network.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.59 n.3 20142014-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000300009en10.4067/S0717-97072014000300009 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
Crystal structure 2,4-dichlorophenoxyacetic acid Cadmium(II) complex |
| spellingShingle |
Crystal structure 2,4-dichlorophenoxyacetic acid Cadmium(II) complex ZHOU,YONG-HONG SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID |
| description |
A new complex [Cd(2,4-D)2(Im)2(H2O)2] with 2,4-dichlorophenoxyacetic acid (2,4-DH) and imidazole (Im) as ligands has been synthesized and characterized by elemental analysis, IR spectrometry and single-crystal X-ray diffraction. The Cd(II) atom is coordinated in a distorted octahedral geometry, which is defined by two O atoms from two monodentate 2,4-dichlorophenoxyacetate ligands, two N atoms from two imidazole ligands and two water molecules. Intermolecular O-H...O hydrogen bonds form chains, which are connected by N-H...O hydrogen bonds, generating a sheet structure. The molecules are further assembled by π...π stacking interactions to form a two dimensional supramolecular network. |
| author |
ZHOU,YONG-HONG |
| author_facet |
ZHOU,YONG-HONG |
| author_sort |
ZHOU,YONG-HONG |
| title |
SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID |
| title_short |
SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID |
| title_full |
SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID |
| title_fullStr |
SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID |
| title_full_unstemmed |
SYNTHESIS, STRUCTURE AND PHOTOLUMINESCENT PROPERTY OF A CADMIUM COMPLEX WITH 2,4-DICHLOROPHENOXYACETIC ACID |
| title_sort |
synthesis, structure and photoluminescent property of a cadmium complex with 2,4-dichlorophenoxyacetic acid |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2014 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000300009 |
| work_keys_str_mv |
AT zhouyonghong synthesisstructureandphotoluminescentpropertyofacadmiumcomplexwith24dichlorophenoxyaceticacid |
| _version_ |
1718445522072633344 |