WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES
Two exhaustive topological analyses using the Electron Localisation Function (ELF) along the non-polar Diels-Alder reactions of 1,3-butadiene [J. Phys. Chem. A107, 6014 (2003)] and cyclopentadiene [Org. Biomol. Chem. 8, 5495, (2010)] with ethylene established that the bonding changes along these rea...
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Sociedad Chilena de Química
2014
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oai:scielo:S0717-970720140003000192014-12-15WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSESDOMINGO,LUIS RTwo exhaustive topological analyses using the Electron Localisation Function (ELF) along the non-polar Diels-Alder reactions of 1,3-butadiene [J. Phys. Chem. A107, 6014 (2003)] and cyclopentadiene [Org. Biomol. Chem. 8, 5495, (2010)] with ethylene established that the bonding changes along these reactions are non-concerted. Herein, the ELF bonding changes along the intramolecular Diels-Alder reaction of 1-(hex-5-enyl)cyclohexa-1,3-diene is analysed. The geometrical restrictions imposed by the tether break the synchronicity in the single bond formation in this non-polar reaction. The present ELF topological analysis along this intramolecular Diels-Alder reaction supports the earlier findings that established the non-concerted nature of Diels-Alder reactions.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.59 n.3 20142014-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000300019en10.4067/S0717-97072014000300019 |
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Scielo Chile |
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Scielo Chile |
| language |
English |
| description |
Two exhaustive topological analyses using the Electron Localisation Function (ELF) along the non-polar Diels-Alder reactions of 1,3-butadiene [J. Phys. Chem. A107, 6014 (2003)] and cyclopentadiene [Org. Biomol. Chem. 8, 5495, (2010)] with ethylene established that the bonding changes along these reactions are non-concerted. Herein, the ELF bonding changes along the intramolecular Diels-Alder reaction of 1-(hex-5-enyl)cyclohexa-1,3-diene is analysed. The geometrical restrictions imposed by the tether break the synchronicity in the single bond formation in this non-polar reaction. The present ELF topological analysis along this intramolecular Diels-Alder reaction supports the earlier findings that established the non-concerted nature of Diels-Alder reactions. |
| author |
DOMINGO,LUIS R |
| spellingShingle |
DOMINGO,LUIS R WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES |
| author_facet |
DOMINGO,LUIS R |
| author_sort |
DOMINGO,LUIS R |
| title |
WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES |
| title_short |
WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES |
| title_full |
WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES |
| title_fullStr |
WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES |
| title_full_unstemmed |
WHY DIELS-ALDER REACTIONS ARE NON-CONCERTED PROCESSES |
| title_sort |
why diels-alder reactions are non-concerted processes |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2014 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072014000300019 |
| work_keys_str_mv |
AT domingoluisr whydielsalderreactionsarenonconcertedprocesses |
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