RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST

A new rapid and efficient method for the synthesis of a series of alkylated phloroglucinols using conventional microwave is reported 4 phloroglucinol derivatives (4, 5, 6 and 7) were synthesized with good yields (~50%) by a Friedel-Crafts reaction through an Electrophilic Aromatic Substitution mecha...

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Autores principales:	VERGARA,ALEJANDRA P, CONTRERAS,JAVIER A, OSORIO,MAURICIO E, CARVAJAL,MARCELA A
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2015
Materias:	Microwave synthesis alkylated phloroglucinol AgNO3
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000300020
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spelling	oai:scielo:S0717-970720150003000202015-12-04RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYSTVERGARA,ALEJANDRA PCONTRERAS,JAVIER AOSORIO,MAURICIO ECARVAJAL,MARCELA A Microwave synthesis alkylated phloroglucinol AgNO3 A new rapid and efficient method for the synthesis of a series of alkylated phloroglucinols using conventional microwave is reported 4 phloroglucinol derivatives (4, 5, 6 and 7) were synthesized with good yields (~50%) by a Friedel-Crafts reaction through an Electrophilic Aromatic Substitution mechanism between geraniol/prenol and phloroglucinol, using reusable SiO2 and AgNO3 as the best catalyst tested without solvents under microwave irradiation.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.60 n.3 20152015-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000300020en10.4067/S0717-97072015000300020
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Microwave synthesis alkylated phloroglucinol AgNO3
spellingShingle	Microwave synthesis alkylated phloroglucinol AgNO3 VERGARA,ALEJANDRA P CONTRERAS,JAVIER A OSORIO,MAURICIO E CARVAJAL,MARCELA A RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST
description	A new rapid and efficient method for the synthesis of a series of alkylated phloroglucinols using conventional microwave is reported 4 phloroglucinol derivatives (4, 5, 6 and 7) were synthesized with good yields (~50%) by a Friedel-Crafts reaction through an Electrophilic Aromatic Substitution mechanism between geraniol/prenol and phloroglucinol, using reusable SiO2 and AgNO3 as the best catalyst tested without solvents under microwave irradiation.
author	VERGARA,ALEJANDRA P CONTRERAS,JAVIER A OSORIO,MAURICIO E CARVAJAL,MARCELA A
author_facet	VERGARA,ALEJANDRA P CONTRERAS,JAVIER A OSORIO,MAURICIO E CARVAJAL,MARCELA A
author_sort	VERGARA,ALEJANDRA P
title	RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST
title_short	RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST
title_full	RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST
title_fullStr	RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST
title_full_unstemmed	RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST
title_sort	rapid method of friedel-crafts alkylation of phloroglucinol by microwave in dry media and reusable catalyst
publisher	Sociedad Chilena de Química
publishDate	2015
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000300020
work_keys_str_mv	AT vergaraalejandrap rapidmethodoffriedelcraftsalkylationofphloroglucinolbymicrowaveindrymediaandreusablecatalyst AT contrerasjaviera rapidmethodoffriedelcraftsalkylationofphloroglucinolbymicrowaveindrymediaandreusablecatalyst AT osoriomauricioe rapidmethodoffriedelcraftsalkylationofphloroglucinolbymicrowaveindrymediaandreusablecatalyst AT carvajalmarcelaa rapidmethodoffriedelcraftsalkylationofphloroglucinolbymicrowaveindrymediaandreusablecatalyst
_version_	1718445541099044864

RAPID METHOD OF FRIEDEL-CRAFTS ALKYLATION OF PHLOROGLUCINOL BY MICROWAVE IN DRY MEDIA AND REUSABLE CATALYST

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